[QE-users] Problem with ph.x

Carlos Reis carlos.loia.reis at gmail.com
Tue Mar 23 18:12:29 CET 2021


Dear Willem

Thank you very much for your suggestion of themo_pw.

This package has a nice feature that does exactly what I want.

I ran thermo_pw with this control file

&INPUT_THERMO
 find_ibrav=.TRUE.
  what='scf',
 /

using a pw.x input file with ibrav=0 , unit cell vectors and atomic
positions referred to original vectors
(which is what I have) the program outputs the correct ibrav, celldm, and
atomic positions referred to allat.

so apparently it solves my problem!

described here

https://people.sissa.it/~dalcorso/thermo_pw/tutorial/node4.html

Best regards,
Carlos Reis.



On Tue, Mar 23, 2021 at 11:00 AM Offermans Willem <willem.offermans at vito.be>
wrote:

> Dear Carlos and Quantum Espresso friends,
>
> In the past, I had severe problems with symmetry detection by Quantum
> Espresso.
> I’m studying stepped surfaces, such as Pt(221) and Pt(533) with S_2
> symmetry.
> Depending on how I define the unit cell and the positions of the slab
> atoms therein,
> QE could or could not detect right symmetry.
>
> Someone pointed out to use gener_3d_slab tool from thermo_pw to generate
> the structures. Indeed, the structures generated by gener_3d_slab are
> better
> handled by QE with respect to symmetry detection, but it is not 100% user
> proof.
> Even now, I have systems where I start with relaxing a structure with S2
> symmetry,
> but loosing the symmetry upon restarts of the calculations. In the latter
> case, I need
> to redefine the positions of the slab atoms to regenerate the right
> symmetry.
>
> B.t.w. thermo_pw is located here:
>
> https://github.com/dalcorso/thermo_pw
>
>
>
>
> Met vriendelijke groeten,
> Mit freundlichen Grüßen,
> With kind regards,
>
>
> Willem Offermans
> Researcher Electrocatalysis SCT
> VITO NV | Boeretang 200 | 2400 Mol
> Phone:+32(0)14335263 Mobile:+32(0)492182073
>
> Willem.Offermans at Vito.be
>
>
> On 23 Mar 2021, at 10:45, Carlos Reis <carlos.loia.reis at gmail.com> wrote:
>
> Dear Paolo
>
> Thank you very much for your feedback.
>
> Is there any tool that I can use to convert the unit cell vectors and
> atomic positions in a format so that q-e recognize the correct symmetry and
> generates the appropriate input for q-e?
>
> Best regards,
> Carlos Reis.
>
>
> On Mon, Mar 22, 2021 at 8:50 PM Paolo Giannozzi <p.giannozzi at gmail.com>
> wrote:
>
>> Well, no, it's the same problem that was reported some time ago. Your
>> lattice has a higher symmetry (tetragonal I) than triclinic (ibrav=14):
>>    ibrav     = 7, celldm(1) =     16.22739617, celldm(3) =      0.6324556
>> corresponding to crystal axes (alat units)
>>                a(1) = (   0.500000  -0.500000   0.316228 )
>>                a(2) = (   0.500000   0.500000   0.316228 )
>>                a(3) = (  -0.500000  -0.500000   0.316228 )
>> with atomic positions (no warranty):
>> ATOMIC_POSITIONS {alat}
>>          Si  0.0000000   0.0000000   0.0000000
>>          Si  0.4000000   0.8000000   0.0000000
>>          Si  0.6000000   0.2000000   0.0000000
>>          Si  0.2000000   0.4000000   0.0000000
>>          Si  1.0000000   0.5000000   0.1581139
>>          Si  0.6000000   0.7000000   0.1581139
>>          Si  0.4000000   0.3000000   0.1581139
>>          Si  0.2000000  -0.1000000   0.1581139
>>          C   0.8000000   0.6000000   0.0000000
>>          C   0.8000000   0.1000000   0.1581139
>>
>> The symmetry searching algorithm detects one symmetry, in addition to the
>> identity, and this is compatible with the FFT grid computed for the
>> tetragonal I lattice (48 48 48: the three lattice vectors have the same
>> length), but not for the triclinic lattice (60 60 48: two vectors have the
>> same length, different from the third).
>>
>> Paolo
>>
>> On Mon, Mar 22, 2021 at 9:35 AM Paolo Giannozzi <p.giannozzi at gmail.com>
>> wrote:
>>
>>> Very strange. I have opened an item in the "Issues" section:
>>>    https://gitlab.com/QEF/q-e/-/issues/301
>>> <https://eur02.safelinks.protection.outlook.com/?url=https%3A%2F%2Fgitlab.com%2FQEF%2Fq-e%2F-%2Fissues%2F301&data=04%7C01%7C%7C3e970cb398c54300185008d8ede08d6b%7C9e2777ed82374ab992782c144d6f6da3%7C0%7C1%7C637520896009277291%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C3000&sdata=jl2RQMMdINdF%2Funia4Q%2F1rj%2FD3P1XPyOjMMbMY%2Fe%2FsA%3D&reserved=0>
>>> Paolo
>>>
>>> On Tue, Mar 16, 2021 at 7:26 PM Carlos Reis <carlos.loia.reis at gmail.com>
>>> wrote:
>>>
>>>> Hello
>>>>
>>>> I use this file to perform a scf calculation
>>>>
>>>> &CONTROL
>>>>   calculation = 'scf',
>>>>    pseudo_dir = '.',
>>>>    wf_collect = .true.,
>>>> /
>>>> &SYSTEM
>>>>   ibrav     = 14,
>>>>  celldm(1) =     16.22739617
>>>>  celldm(2) =      1.00000000
>>>>  celldm(3) =      0.77459667
>>>>  celldm(4) =      0.64549723
>>>>  celldm(5) =      0.64549723
>>>>         nat =    10 ,
>>>>        ntyp =     2 ,
>>>>        nbnd =    28 ,
>>>>     ecutwfc =         30.000 ,
>>>> /
>>>> &ELECTRONS
>>>>   diagonalization = 'david',
>>>> /
>>>> ATOMIC_SPECIES
>>>> Si        28.085500                   Si.UPF
>>>> C         12.011000                    C.UPF
>>>> ATOMIC_POSITIONS {crystal}
>>>>    Si          -0.00000000     -0.00000000      0.00000000
>>>>    Si           0.40000000      0.80000000      0.00000000
>>>>    Si           0.60000000      0.20000000      0.00000000
>>>>    Si           0.20000000      0.40000000      0.00000000
>>>>    Si           0.75000000      0.25000000      0.50000000
>>>>    Si           0.35000000      0.45000000      0.50000000
>>>>    Si           0.15000000      0.05000000      0.50000000
>>>>    Si          -0.05000000     -0.35000000      0.50000000
>>>>    C            0.80000000      0.60000000      0.00000000
>>>>    C            0.55000000     -0.15000000      0.50000000
>>>> K_POINTS {automatic}
>>>>        4       4       4       1       1       1
>>>>
>>>> and then I run ph.x with this input file:
>>>>
>>>> --
>>>> &inputph
>>>>   prefix   = 'pwscf',
>>>>   epsil    = .false.,
>>>>   fildyn   = 'pwscf.dyn',
>>>>   ldisp    = .true.
>>>>   fildvscf = 'dvscf'
>>>>   nq1=1,
>>>>   nq2=1,
>>>>   nq3=1,
>>>>  /
>>>>
>>>>     Program PHONON v.6.7MaX starts on 16Mar2021 at 17:18:57
>>>>
>>>>      This program is part of the open-source Quantum ESPRESSO suite
>>>>      for quantum simulation of materials; please cite
>>>>          "P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502
>>>> (2009);
>>>>          "P. Giannozzi et al., J. Phys.:Condens. Matter 29 465901
>>>> (2017);
>>>>           URL http://www.quantum-espresso.org
>>>> <https://eur02.safelinks.protection.outlook.com/?url=http%3A%2F%2Fwww.quantum-espresso.org%2F&data=04%7C01%7C%7C3e970cb398c54300185008d8ede08d6b%7C9e2777ed82374ab992782c144d6f6da3%7C0%7C1%7C637520896009287289%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C3000&sdata=rOZrqPqvGT%2BQImKZ4wNCI033D2AiNFgh948QsjBrNuQ%3D&reserved=0>
>>>> ",
>>>>      in publications or presentations arising from this work. More
>>>> details at
>>>>      http://www.quantum-espresso.org/quote
>>>> <https://eur02.safelinks.protection.outlook.com/?url=http%3A%2F%2Fwww.quantum-espresso.org%2Fquote&data=04%7C01%7C%7C3e970cb398c54300185008d8ede08d6b%7C9e2777ed82374ab992782c144d6f6da3%7C0%7C1%7C637520896009287289%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C3000&sdata=4Oqhdt5NF54XRdTs%2F%2BV7mAKE0uFgGVMRU6yt3aJjPQw%3D&reserved=0>
>>>>
>>>>      Parallel version (MPI), running on    16 processors
>>>>
>>>>      MPI processes distributed on     1 nodes
>>>>      K-points division:     npool     =      16
>>>>      Waiting for input...
>>>>      Reading input from standard input
>>>>
>>>>      Reading xml data from directory:
>>>>
>>>>      ./pwscf.save/
>>>>      file C.UPF: wavefunction(s)  3d renormalized
>>>>
>>>>      IMPORTANT: XC functional enforced from input :
>>>>      Exchange-correlation= PZ
>>>>                            (   1   1   0   0   0   0   0)
>>>>      Any further DFT definition will be discarded
>>>>      Please, verify this is what you really want
>>>>
>>>>
>>>>      G-vector sticks info
>>>>      --------------------
>>>>      sticks:   dense  smooth     PW     G-vecs:    dense   smooth
>>>>  PW
>>>>      Sum        2521    2521    821                30009    30009
>>>>  5631
>>>>
>>>>      Reading collected, re-writing distributed wavefunctions
>>>>
>>>>
>>>>      Dynamical matrices for ( 1, 1, 1)  uniform grid of q-points
>>>>      (   1 q-points):
>>>>        N         xq(1)         xq(2)         xq(3)
>>>>        1   0.000000000   0.000000000   0.000000000
>>>>
>>>>      Saving dvscf to file. Distribute only q points, not irreducible
>>>> represetations.
>>>>
>>>>      Calculation of q =    0.0000000   0.0000000   0.0000000
>>>>      warning: symmetry operation #  2 not compatible with FFT grid.
>>>>    1   0   0
>>>>    0   1   0
>>>>    1   1  -1
>>>>
>>>>
>>>>  %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
>>>>
>>>>
>>>>  %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
>>>>      Error in routine phq_setup (1):
>>>>      FFT grid incompatible with symmetry
>>>>
>>>>  %%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
>>>>
>>>>
>>>> Is there any way to easily fix this? should I have to manually specify
>>>> nr1, nr2, nr3?
>>>>
>>>> Any help is appreciated.
>>>>
>>>> Best regards,
>>>> Carlos Reis.
>>>>
>>>>
>>>>
>>>> _______________________________________________
>>>> Quantum ESPRESSO is supported by MaX (www.max-centre.eu
>>>> <https://eur02.safelinks.protection.outlook.com/?url=http%3A%2F%2Fwww.max-centre.eu%2F&data=04%7C01%7C%7C3e970cb398c54300185008d8ede08d6b%7C9e2777ed82374ab992782c144d6f6da3%7C0%7C1%7C637520896009297283%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C3000&sdata=S252VMrRkZGUReX8FVAWyU7WKhIIEd6mqKHQfX7IaFc%3D&reserved=0>
>>>> )
>>>> users mailing list users at lists.quantum-espresso.org
>>>> https://lists.quantum-espresso.org/mailman/listinfo/users
>>>> <https://eur02.safelinks.protection.outlook.com/?url=https%3A%2F%2Flists.quantum-espresso.org%2Fmailman%2Flistinfo%2Fusers&data=04%7C01%7C%7C3e970cb398c54300185008d8ede08d6b%7C9e2777ed82374ab992782c144d6f6da3%7C0%7C1%7C637520896009297283%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C3000&sdata=g6csiaIYbw01zI2KzV%2F%2FqiOnS%2BTAEdiC5ooOwCDP5Js%3D&reserved=0>
>>>
>>>
>>>
>>> --
>>> Paolo Giannozzi, Dip. Scienze Matematiche Informatiche e Fisiche,
>>> Univ. Udine, via delle Scienze 206, 33100 Udine, Italy
>>> Phone +39-0432-558216, fax +39-0432-558222
>>>
>>>
>>
>> --
>> Paolo Giannozzi, Dip. Scienze Matematiche Informatiche e Fisiche,
>> Univ. Udine, via delle Scienze 206, 33100 Udine, Italy
>> Phone +39-0432-558216, fax +39-0432-558222
>>
>> _______________________________________________
>> Quantum ESPRESSO is supported by MaX (www.max-centre.eu
>> <https://eur02.safelinks.protection.outlook.com/?url=http%3A%2F%2Fwww.max-centre.eu%2F&data=04%7C01%7C%7C3e970cb398c54300185008d8ede08d6b%7C9e2777ed82374ab992782c144d6f6da3%7C0%7C1%7C637520896009297283%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C3000&sdata=S252VMrRkZGUReX8FVAWyU7WKhIIEd6mqKHQfX7IaFc%3D&reserved=0>
>> )
>> users mailing list users at lists.quantum-espresso.org
>> https://lists.quantum-espresso.org/mailman/listinfo/users
>> <https://eur02.safelinks.protection.outlook.com/?url=https%3A%2F%2Flists.quantum-espresso.org%2Fmailman%2Flistinfo%2Fusers&data=04%7C01%7C%7C3e970cb398c54300185008d8ede08d6b%7C9e2777ed82374ab992782c144d6f6da3%7C0%7C1%7C637520896009307282%7CUnknown%7CTWFpbGZsb3d8eyJWIjoiMC4wLjAwMDAiLCJQIjoiV2luMzIiLCJBTiI6Ik1haWwiLCJXVCI6Mn0%3D%7C3000&sdata=YiI72LBhBJ0iY66gUvuzzvL5urceFP55eIfjhhuvcDY%3D&reserved=0>
>
> _______________________________________________
> Quantum ESPRESSO is supported by MaX (www.max-centre.eu)
> users mailing list users at lists.quantum-espresso.org
> https://lists.quantum-espresso.org/mailman/listinfo/users
>
>
> _______________________________________________
> Quantum ESPRESSO is supported by MaX (www.max-centre.eu)
> users mailing list users at lists.quantum-espresso.org
> https://lists.quantum-espresso.org/mailman/listinfo/users
-------------- next part --------------
An HTML attachment was scrubbed...
URL: <http://lists.quantum-espresso.org/pipermail/users/attachments/20210323/a9ffd2e6/attachment.html>
-------------- next part --------------
A non-text attachment was scrubbed...
Name: vito.jpg
Type: image/jpeg
Size: 15232 bytes
Desc: not available
URL: <http://lists.quantum-espresso.org/pipermail/users/attachments/20210323/a9ffd2e6/attachment.jpg>


More information about the users mailing list