[QE-users] Variation in ph.x results for QE 6.5 and QE 6.4
Offermans Willem
willem.offermans at vito.be
Mon Sep 14 09:42:32 CEST 2020
Dear QE friends and Paolo,
I’m sorry to break into this mail thread, but could you elaborate a bit on “applying acoustic sum rule”.
How is this done?
Met vriendelijke groeten,
Mit freundlichen Grüßen,
With kind regards,
Willem Offermans
Researcher Electrocatalysis SCT
VITO NV | Boeretang 200 | 2400 Mol
Phone:+32(0)14335263 Mobile:+32(0)492182073
Willem.Offermans at Vito.be<mailto:Willem.Offermans at Vito.be>
[cid:982BA063-B96A-4A1B-89AB-5A01CA9FC70D at vito.local]
On 14 Sep 2020, at 08:34, Paolo Giannozzi <p.giannozzi at gmail.com<mailto:p.giannozzi at gmail.com>> wrote:
Apparently the largest discrepancies come from low-energy modes, in particular zero-frequency acoustic modes (those with "negative" frequencies that become zero when acoustic sum rule is applied). Even minor changes in the way exchange-correlation is computed may lead to surprisingly large but unphysical differences for those modes.
Paolo
On Sun, Sep 13, 2020 at 7:54 PM Unmesh Mondal <unmesh.mondal at students.iiserpune.ac.in<mailto:unmesh.mondal at students.iiserpune.ac.in>> wrote:
Dear all,
I intend to calculate the vibrational modes of gas phase HCOOH (formic acid) molecule.
The "ph.x" vibrational frequencies (in cm-1) of the system for the two versions of quantum espresso (6.5 and 6.4 : with same compilers) are:
(QE 6.5) (QE 6.4)
1 -207.654081 -207.686563
2 -63.775769 -61.840758
3 -55.090067 -57.158594
4 -15.183543 -15.903109
5 20.311666 21.386665
6 129.683418 129.214185
7 615.352300 615.209434
8 676.597853 676.547298
9 999.285772 999.331118
10 1071.840671 1071.779138
11 1253.496419 1253.514267
12 1350.618940 1350.925730
13 1735.698557 1735.582574
14 2965.285270 2965.885980
15 3665.961548 3665.948232
The maximum difference in any frequency for the two versions is about 2 cm-1. My question:
Is the difference of 2 cm-1 within the error limit of ph.x calculations? What is the accuracy we expect in reporting the vibrational frequency (via ph.x)?
Regards and Thanks
Unmesh Mondal
IISER Pune, India
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Paolo Giannozzi, Dip. Scienze Matematiche Informatiche e Fisiche,
Univ. Udine, via delle Scienze 208, 33100 Udine, Italy
Phone +39-0432-558216, fax +39-0432-558222
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