[QE-users] I don't know how to add empty bands and broaden my super cell

Coralie Khabbaz khabbaz.coralie at gmail.com
Thu Jun 18 02:25:00 CEST 2020


Hello vahid,

Thank you so much for your answer! As I am performing an scf calculation,
nbd is not in my input file (I have pasted my input file at the end).
Should I just write nbd=... in the &System part of my input file?
As for the smearing, what do you mean by degauss? Currently, I have
specified a gaussian smearing for my file. Is this okay?

This is my input file:
&CONTROL
    calculation  = "scf"
    max_seconds  =  1.72800e+05
    pseudo_dir   = "/Users/coralie/.burai/.pseudopot"
    restart_mode = "from_scratch"
/

&SYSTEM
    a                         =  1.24907e+01
    angle1(1)                 =  0.00000e+00
    angle1(2)                 =  0.00000e+00
    angle2(1)                 =  0.00000e+00
    angle2(2)                 =  0.00000e+00
    b                         =  1.34803e+01
    c                         =  2.52767e+01
    cosab                     =  6.12323e-17
    cosac                     =  6.12323e-17
    cosbc                     = -1.85547e-01
    degauss                   =  2.00000e-02
    ecutrho                   =  4.75221e+02
    ecutwfc                   =  5.03902e+01
    ibrav                     = 14
    nat                       = 113
    nspin                     = 2
    ntyp                      = 4
    occupations               = "smearing"
    smearing                  = "fermi-dirac"
    starting_magnetization(1) =  2.00000e-01
    starting_magnetization(2) =  6.00000e-01
    starting_magnetization(3) =  0.00000e+00
    starting_magnetization(4) =  0.00000e+00
/

&ELECTRONS
    conv_thr         =  1.00000e-06
    diagonalization  = "david"
    electron_maxstep = 528
    mixing_beta      =  1.41935e-01
    mixing_mode      = "local-TF"
    startingpot      = "atomic"
    startingwfc      = "atomic+random"
/

K_POINTS {automatic}
 4  4  2  0 0 0

ATOMIC_SPECIES
N      14.00674  N.pbe-n-rrkjus_psl.1.0.0.UPF
W     183.84000  W.pbe-spn-rrkjus_psl.1.0.0.UPF
C      12.01070  C.pbe-n-rrkjus_psl.1.0.0.UPF
H       1.00794  H.pbe-rrkjus_psl.1.0.0.UPF

ATOMIC_POSITIONS {angstrom}
N       3.059711   0.418242  14.837784
N       7.223291   0.418242  14.837784
N      11.386870   0.418242  14.837784
N       3.059711   4.911686  14.837784
N       7.223291   4.911686  14.837784
N      11.386870   4.911686  14.837784
N       3.059711   9.405131  14.837784
N       7.223291   9.405131  14.837784
N      11.386870   9.405131  14.837784
W       3.059711   2.628097  14.748648
W       7.223291   2.628097  14.748648
W      11.386870   2.628097  14.748648
W       3.059711   7.121541  14.748648
W       7.223291   7.121541  14.748648
W      11.386870   7.121541  14.748648
W       3.059711  -1.865347  14.748648
W       7.223291  -1.865347  14.748648
W      11.386870  -1.865347  14.748648
N       0.977921   3.110895  14.468179
N       5.141501   3.110895  14.468179
N       9.305080   3.110895  14.468179
N       0.977921   7.604339  14.468179
N       5.141501   7.604339  14.468179
N       9.305080   7.604339  14.468179
N       0.977921  -1.382549  14.468179
N       5.141501  -1.382549  14.468179
N       9.305080  -1.382549  14.468179
W       0.977921   0.783425  14.415413
W       5.141501   0.783425  14.415413
W       9.305080   0.783425  14.415413
W       0.977921   5.276869  14.415413
W       5.141501   5.276869  14.415413
W       9.305080   5.276869  14.415413
W       0.977921   9.770314  14.415413
W       5.141501   9.770314  14.415413
W       9.305080   9.770314  14.415413
N       3.059711   3.081849  12.630078
N       7.223291   3.081849  12.630078
N      11.386870   3.081849  12.630078
N       3.059711   7.575293  12.630078
N       7.223291   7.575293  12.630078
N      11.386870   7.575293  12.630078
N       3.059711  -1.411595  12.630078
N       7.223291  -1.411595  12.630078
N      11.386870  -1.411595  12.630078
W       3.059711   0.798260  12.540942
W       7.223291   0.798260  12.540942
W      11.386870   0.798260  12.540942
W       3.059711   5.291704  12.540942
W       7.223291   5.291704  12.540942
W      11.386870   5.291704  12.540942
W       3.059711   9.785148  12.540942
W       7.223291   9.785148  12.540942
W      11.386870   9.785148  12.540942
N       0.977921   1.281057  12.260473
N       5.141501   1.281057  12.260473
N       9.305080   1.281057  12.260473
N       0.977921   5.774502  12.260473
N       5.141501   5.774502  12.260473
N       9.305080   5.774502  12.260473
N       0.977921  10.267946  12.260473
N       5.141501  10.267946  12.260473
N       9.305080  10.267946  12.260473
W       0.977921   3.447032  12.207706
W       5.141501   3.447032  12.207706
W       9.305080   3.447032  12.207706
W       0.977921   7.940476  12.207706
W       5.141501   7.940476  12.207706
W       9.305080   7.940476  12.207706
W       0.977921  -1.046412  12.207706
W       5.141501  -1.046412  12.207706
W       9.305080  -1.046412  12.207706
N       3.059711   1.252012  10.422372  0 0 0
N       7.223291   1.252012  10.422372  0 0 0
N      11.386870   1.252012  10.422372  0 0 0
N       3.059711   5.745456  10.422372  0 0 0
N       7.223291   5.745456  10.422372  0 0 0
N      11.386870   5.745456  10.422372  0 0 0
N       3.059711  10.238900  10.422372  0 0 0
N       7.223291  10.238900  10.422372  0 0 0
N      11.386870  10.238900  10.422372  0 0 0
W       3.059711   3.461867  10.333236  0 0 0
W       7.223291   3.461867  10.333236  0 0 0
W      11.386870   3.461867  10.333236  0 0 0
W       3.059711   7.955311  10.333236  0 0 0
W       7.223291   7.955311  10.333236  0 0 0
W      11.386870   7.955311  10.333236  0 0 0
W       3.059711  -1.031577  10.333236  0 0 0
W       7.223291  -1.031577  10.333236  0 0 0
W      11.386870  -1.031577  10.333236  0 0 0
N       0.977921   3.944664  10.052766  0 0 0
N       5.141501   3.944664  10.052766  0 0 0
N       9.305080   3.944664  10.052766  0 0 0
N       0.977921   8.438108  10.052766  0 0 0
N       5.141501   8.438108  10.052766  0 0 0
N       9.305080   8.438108  10.052766  0 0 0
N       0.977921  -0.548780  10.052766  0 0 0
N       5.141501  -0.548780  10.052766  0 0 0
N       9.305080  -0.548780  10.052766  0 0 0
W       0.977921   1.617195  10.000000  0 0 0
W       5.141501   1.617195  10.000000  0 0 0
W       9.305080   1.617195  10.000000  0 0 0
W       0.977921   6.110639  10.000000  0 0 0
W       5.141501   6.110639  10.000000  0 0 0
W       9.305080   6.110639  10.000000  0 0 0
W       0.977921  10.604083  10.000000  0 0 0
W       5.141501  10.604083  10.000000  0 0 0
W       9.305080  10.604083  10.000000  0 0 0
C       7.223291   2.628097  19.750000
H       6.590292   1.997000  20.383000
H       7.856291   1.997000  19.117000
H       6.590292   3.263000  19.117000
H       7.856291   3.263000  20.383000



On Wed, 17 Jun 2020 at 19:51, Vahid Askarpour <vh261281 at dal.ca> wrote:

> Specify nbnd for bands.
> For broadening, check the input parameters occupations, smearing, degauss.
>
> Cheers,
> Vahid
>
> Vahid Askarpour
> Department of physics and atmospheric science
> Dalhousie University
> Halifax, NS
> Canada
>
> On Jun 17, 2020, at 8:44 PM, Coralie Khabbaz <khabbaz.coralie at gmail.com>
> wrote:
>
> CAUTION: The Sender of this email is not from within Dalhousie.
> I am performing an SCF calculation (on a tungsten nitride slab that
> contains 114 atoms) that is not converging. I was told that I had to add
> a few empty bands and a broadening. However, I don't know how to do that as
> I am still a beginner. How do I add empty bands and how do I broaden?
> Please help!!
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