[QE-users] Error in routine cdiaghg (3448): S matrix not positive definite

Natalia Kireeva nkireeva at gmail.com
Fri Dec 6 11:04:42 CET 2019


Dear Quantum Espresso Community,


We try to launch pw.x (Quantum Espresso 6.4.1) for the calculations of the
garnet-structured compound LLZO varying the lattice constant to assess the
impact of strain. The aim of our calculations is to assess the possibility
stabilizing the cubic polymorph of LLZO by the applied tensile or
compressive strain.

The calculations are interrrupted by the error message:


Error in routine cdiaghg (3448):

S matrix not positive definite

We try to launch the calculations using different lattice constants,
different ways of atomic coordinates description, varying the kinetic
energy cut-off, changing the pseudopotentials as well as the number of
k-points. The text of error is always the same the number of error can
differ (here, 3448).

We would be grateful for your help.


&CONTROL

calculation = 'scf' ,

restart_mode = 'from_scratch' ,

outdir = '/home/wakeup/Playground/qe-6.4.1/' ,

wfcdir = '/home/wakeup/Playground/qe-6.4.1/' ,

pseudo_dir =
'/home/wakeup/Playground/qe-6.4.1/pseudo/pslibrary-master/pbe/PSEUDOPOTENTIALS/'
,

prefix = 'LLZO' ,

disk_io = 'high' ,

verbosity = 'high' ,

/

&SYSTEM

ibrav = 3,

celldm(1) = 12.965,

nat = 485,

ntyp = 4,

ecutwfc = 100 ,

ecutrho = 400 ,

/

&ELECTRONS

/

ATOMIC_SPECIES

La 138.91000 La.pbe-spdfn-kjpaw_psl.1.0.0.UPF

Zr 92.91000 Zr.pbe-spn-kjpaw_psl.1.0.0.UPF

Li 47.90000 Li.pbe-s-kjpaw_psl.1.0.0.UPF

O 15.99900 O.pbe-n-kjpaw_psl.1.0.0.UPF

ATOMIC_POSITIONS angstrom

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O 6.901816000 0.711474000 -1.944868000

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O 8.436419000 0.410266000 13.694574000

O 4.546681000 12.572834000 -0.711474000

O 5.780076000 14.927968000 0.410266000

O 6.901816000 13.694574000 -1.944868000

O 6.081284000 12.271626000 14.927968000

O 5.780076000 14.927968000 13.393366000

O -1.944868000 -0.410266000 7.203024000

O 0.711474000 -1.944868000 6.901816000

O -1.944868000 12.572834000 7.203024000

O -0.711474000 14.927968000 6.081284000

O 0.410266000 13.694574000 8.436419000

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O 14.927968000 0.410266000 5.780076000

O 12.271626000 14.927968000 6.081284000

O 14.927968000 13.393366000 5.780076000

Li 14.268427000 2.427840000 5.543784000

Li -1.285327000 10.555260000 7.439316000

Li -1.285327000 8.919390000 0.947766000

Li 14.268427000 4.063710000 12.035334000

Li 5.543784000 14.268427000 2.427840000

Li 7.439316000 -1.285327000 10.555260000

Li 0.947766000 -1.285327000 8.919390000

Li 12.035334000 14.268427000 4.063710000

Li 2.427840000 5.543784000 14.268427000

Li 10.555260000 7.439316000 -1.285327000

Li 8.919390000 0.947766000 -1.285327000

Li 4.063710000 12.035334000 14.268427000

Li -1.285327000 4.063710000 5.543784000

Li 14.268427000 8.919390000 7.439316000

Li 14.268427000 10.555260000 0.947766000

Li -1.285327000 2.427840000 12.035334000

Li 5.543784000 -1.285327000 4.063710000

Li 7.439316000 14.268427000 8.919390000

Li 0.947766000 14.268427000 10.555260000

Li 12.035334000 -1.285327000 2.427840000

Li 4.063710000 5.543784000 -1.285327000

Li 8.919390000 7.439316000 14.268427000

Li 10.555260000 0.947766000 14.268427000

Li 2.427840000 12.035334000 -1.285327000

K_POINTS automatic

2 2 1 1 1 1
_____________________________________________________
Natalia KIREEVA, PhD,
Frumkin Insitute of Physical Chemistry and Electrochemistry RAS
tel. (+7) 916-8257704
e-mail: nkireeva at gmail.com; kireeva at phyche.ac.ru
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