[Pw_forum] Convergence problem in NEB

Junning Li johnnyli4 at outlook.com
Thu Jul 16 15:32:28 CEST 2015


Dear All,
     I met a problem of convergence in NEB calculation. The calculation ended in a quite beginning time saying one of the images didn't converged. The input and output files are attached.

     The tail of the output file is follow:
---------------------------------------------------------------------------------


     cpu =  0   tcpu =   5281.3    self-consistency for image   2

     WARNING :  scf convergence NOT achieved on image   2

     cleaning-up extrapolation files

 
     NEB          :     1h31m CPU        1h40m WALL

 
   This run was terminated on:   9:35: 9   9Jul2015            

=------------------------------------------------------------------------------=
   JOB DONE.
=------------------------------------------------------------------------------

My input file content is following:
--------------------------------------------------------------------------------
BEGIN
BEGIN_PATH_INPUT
&PATH
  restart_mode      = 'from_scratch'
  string_method     = 'neb',
  nstep_path        = 100,
  ds                = 2.D0,
  opt_scheme        = "broyden",
  num_of_images     = 5,
  k_max             = 0.3D0,
  k_min             = 0.2D0,
  CI_scheme         = "no-CI",
  path_thr          = 0.1D0,
/
END_PATH_INPUT
BEGIN_ENGINE_INPUT
&CONTROL
  prefix         = c2c2_c2c1+h
  outdir         = "./bin",
  pseudo_dir     = "/public/pseudos_qe",
  max_seconds=172500
/
&SYSTEM
  ibrav                  = 0,
  nat                    = 54,
  ntyp                   = 4,
  ecutwfc                = 34 ,
  ecutrho                = 340 ,
  occupations='smearing', smearing='mp', degauss=0.012
  input_dft = 'rvv10'
/
&ELECTRONS
  mixing_mode = 'local-TF'
  conv_thr = 1.0e-8
  mixing_beta = 0.7
/
ATOMIC_SPECIES
Al  26.9815385  Al.pbe-n-van.UPF
Ni  58.6934     Ni.pbe-nd-rrkjus.UPF
H   1.00794     H.pbe-rrkjus.UPF
C    12.01115     C.pbe-rrkjus.UPF
BEGIN_POSITIONS
FIRST_IMAGE
ATOMIC_POSITIONS (angstrom)
Ni       6.321923530   3.649964250   4.935268420    0   0   0
Ni       5.057538830   1.459985700   4.935268420    0   0   0
Ni       3.793154120   3.649964250   4.935268420    0   0   0
Ni       8.850692943   8.029921354   4.935268420    0   0   0
Ni       7.586308243   5.839942804   4.935268420    0   0   0
Ni       6.321923533   8.029921354   4.935268420    0   0   0
Ni      11.379462356   3.649964250   4.935268420    0   0   0
Ni      10.115077656   1.459985700   4.935268420    0   0   0
Ni       8.850692946   3.649964250   4.935268420    0   0   0
Ni      13.908231769   8.029921354   4.935268420    0   0   0
Ni      12.643847069   5.839942804   4.935268420    0   0   0
Ni      11.379462359   8.029921354   4.935268420    0   0   0
Al       2.528769410   1.459985700   4.935268420    0   0   0
Al       5.057538823   5.839942804   4.935268420    0   0   0
Al       7.586308236   1.459985700   4.935268420    0   0   0
Al      10.115077649   5.839942804   4.935268420    0   0   0
Ni       1.276650472   0.746368013   8.979629393
Ni      -0.002291088  -1.442656781   8.995866513
Ni      -1.259856605   0.736080799   8.998058871
Ni       3.800810766   2.200134027   6.955597149
Ni       2.534692369   0.002785525   6.953019276
Ni       1.262476016   2.201313447   6.954326877
Ni       3.803040035   5.130781830   8.994425962
Ni       2.538537151   2.932664491   8.978717542
Ni       1.289845023   5.133477916   8.989765743
Ni       6.324449755   6.568505941   6.982750055
Ni       5.069162565   4.391717813   6.986081303
Ni       3.789359903   6.580437255   6.972983638
Ni       6.338110139   0.743714992   8.996188401
Ni       5.083382614  -1.433503622   8.989914170
Ni       3.801977887   0.747812786   8.979837699
Ni       8.845233170   2.201885794   6.984006850
Ni       7.589046261   0.000090173   6.974341609
Ni       6.333330120   2.201281155   6.986505066
Ni       8.895551399   5.148342272   9.190547319
Ni       7.605817863   2.946065757   9.068710708
Ni       6.343129087   5.128926385   9.068635484
Ni      11.379677820   6.575782661   6.971323507
Ni      10.090059085   4.391481888   6.998090700
Ni       8.845127236   6.551379943   6.995711235
Al       0.002320760   0.007045198   6.964486579
Al       5.046632203   2.922942946   9.009133107
Al       2.529105218   4.388348103   6.960234433
Al       7.590243426   7.348434345   8.996514660
Al       5.061457932   0.004475084   6.960318692
Al      10.149414659   2.913932758   9.003530078
Al       7.588149137   4.387211040   7.010532167
Al      12.654789109   7.315230658   9.060272159
C        8.735489639   5.099531693  11.226741059
C        7.558051610   4.401411922  10.828538185
H        9.576186850   4.535967955  11.629599855
H        7.522429705   3.315126659  11.061522538
H        8.650115069   6.117361652  11.605965160
H        6.585410438   4.903223939  11.037275912
LAST_IMAGE
ATOMIC_POSITIONS (angstrom)
Ni       6.321923530   3.649964250   4.935268420    0   0   0
Ni       5.057538830   1.459985700   4.935268420    0   0   0
Ni       3.793154120   3.649964250   4.935268420    0   0   0
Ni       8.850692943   8.029921354   4.935268420    0   0   0
Ni       7.586308243   5.839942804   4.935268420    0   0   0
Ni       6.321923533   8.029921354   4.935268420    0   0   0
Ni      11.379462356   3.649964250   4.935268420    0   0   0
Ni      10.115077656   1.459985700   4.935268420    0   0   0
Ni       8.850692946   3.649964250   4.935268420    0   0   0
Ni      13.908231769   8.029921354   4.935268420    0   0   0
Ni      12.643847069   5.839942804   4.935268420    0   0   0
Ni      11.379462359   8.029921354   4.935268420    0   0   0
Al       2.528769410   1.459985700   4.935268420    0   0   0
Al       5.057538823   5.839942804   4.935268420    0   0   0
Al       7.586308236   1.459985700   4.935268420    0   0   0
Al      10.115077649   5.839942804   4.935268420    0   0   0
Ni       1.299613009   0.729343045   8.973487915
Ni       0.042668222  -1.452697892   9.059161275
Ni      -1.232650972   0.706248526   8.978690508
Ni       3.812974437   2.192486692   6.953612905
Ni       2.542724553  -0.010559521   6.950733527
Ni       1.275507917   2.189712931   6.951636103
Ni       3.820900456   5.099898326   9.058473844
Ni       2.557198249   2.917250364   8.972465164
Ni       1.316645879   5.124564186   8.982242065
Ni       6.333569310   6.553362185   6.985340606
Ni       5.078145565   4.385350833   6.983065534
Ni       3.811917842   6.570835194   6.984263869
Ni       6.354414187   0.711714841   8.985700898
Ni       5.107814169  -1.449465084   8.986433005
Ni       3.818146748   0.729274423   8.974413246
Ni       8.858789513   2.195831982   6.980052694
Ni       7.604036801  -0.006441142   6.965245164
Ni       6.350206415   2.203465853   6.993611172
Ni       8.939204281   5.117902129   9.156754383
Ni       7.630863065   2.894283540   9.070598880
Ni       6.362667263   5.077489353   9.152021645
Ni      11.400107012   6.573322376   6.965931016
Ni      10.115723983   4.381974040   6.988613199
Ni       8.863393932   6.545055799   6.995022670
Al       0.014861479  -0.007284328   6.964627335
Al       5.055933008   2.894730127   9.017744116
Al       2.547972470   4.385872199   6.964403329
Al       7.622477374   7.324693248   8.994399271
Al       5.074783390  -0.001377500   6.957157418
Al      10.172489367   2.902321932   9.000433335
Al       7.605654322   4.385264463   7.008060741
Al      12.679159749   7.298749906   9.065850421
C        8.460275075   5.118978297  11.273983617
C        7.582419702   4.370181702  10.481717082
H        9.172673172   4.618371293  11.933150506
H        7.537463847   3.264364222  10.813841070
H        8.266622009   6.160322624  11.522100564
H        5.084198241   5.850468857   9.929703951
END_POSITIONS
K_POINTS {automatic}
3 3 1 0 0 0
CELL_PARAMETERS  angstrom
    10.115077652    0.000000000    0.000000000
     5.057538826    8.759914208    0.000000000
     0.000000000    0.000000000   25.000000000
END_ENGINE_INPUT
END
-------------------------------------------------------------------------

I will be grateful if someone help me to go through the problem.

Best regard,

Johnny Li
Department of Physics, 
Wuhan University, 
Hubei, 
China
 		 	   		  
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