[Pw_forum] Non Convergence

Elliot Menkah elliotsmenkah at yahoo.com
Wed Nov 5 16:41:28 CET 2014


Hello Everyone,
I'm running a geometry optimization calculation(relax) of an 11-layer
Nickel slab and I used the deafult nstep (nstep=50) and electron_maxstep
(100).

My system did not converge with the parameters and configurations set as
it run through 100 iterations.

Could there be something wrong with the configuration or would I have to
increase the  electron_maxstep value?.

Please find attached both input and out files in that regard.

Thank you


Kind Regards,

Elliot




-- 
Elliot S. Menkah
Research Student - Computational Chemistry/ Computational Material Science
Theoretical and Computational Chemistry
Dept. of Chemistry
Kwame Nkrumah UNiversity of Sci. and Tech.
Kumasi
Ghana

Tel: +233 243-055-717

Alt Email: elliotsmenkah at gmail.com
           elliotsmenkah at hotmail.com

-------------- next part --------------
&CONTROL
       title = 'MatStu-ni-001-1x1-11L-Arlxd.in' ,
       calculation = 'relax' ,
       restart_mode = 'from_scratch' ,
       outdir = './tmp' ,
       pseudo_dir = '/home/mmc14/pseudo' ,
       prefix = 'ni-100-1x1-11L-allrlxd',
       tstress = .true. ,
       tprnfor = .true. ,
/
 &SYSTEM
       ibrav = 0,
       celldm(1) = 1.8897259,
       nat = 11,
       ntyp = 1,
       ecutwfc = 60,
       ecutrho = 640,
       occupations='smearing',
       smearing='mp',
       degauss=0.005D0,
       nbnd=80,
       nspin=2,
       starting_magnetization(1)=0.5,
/
 &ELECTRONS
        conv_thr = 1.0D-6,
        mixing_beta = 0.2,
        electron_maxstep = 100,
/
 &IONS
/
ATOMIC_SPECIES
Ni1 58.6934   Ni.pbe-nd-rrkjus.UPF
ATOMIC_POSITIONS (crystal)
Ni1        0.00000  -0.00000  -0.00000   
Ni1        0.00000  -0.00000   0.11895   
Ni1        0.00000  -0.00000   0.23789   
Ni1        0.00000  -0.00000   0.35684   
Ni1        0.00000  -0.00000   0.47579   
Ni1        0.00000   0.00000   0.59473   
Ni1        0.50000   0.50000   0.05947   
Ni1        0.50000   0.50000   0.17842   
Ni1        0.50000   0.50000   0.29737   
Ni1        0.50000   0.50000   0.41631   
Ni1        0.50000   0.50000   0.53526   
K_POINTS automatic
  5 5 1   0 0 0
CELL_PARAMETERS
 +2.4904000000  +0.0000000000  +0.0000000000
 +0.0000000000  +2.4904000000  +0.0000000000
  0.0000000000   0.0000000000 +29.6100000000

-------------- next part --------------

     Program PWSCF v.5.0.2 (svn rev. 9392) starts on 29Oct2014 at 18:32:50 

     This program is part of the open-source Quantum ESPRESSO suite
     for quantum simulation of materials; please cite
         "P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502 (2009);
          URL http://www.quantum-espresso.org", 
     in publications or presentations arising from this work. More details at
     http://www.quantum-espresso.org/quote.php

     Serial version

     Current dimensions of program PWSCF are:
     Max number of different atomic species (ntypx) = 10
     Max number of k-points (npk) =  40000
     Max angular momentum in pseudopotentials (lmaxx) =  3
     Waiting for input...
     Reading input from standard input
               file Ni.pbe-nd-rrkjus.UPF: wavefunction(s)  4S renormalized

     G-vector sticks info
     --------------------
     sticks:   dense  smooth     PW     G-vecs:    dense   smooth      PW
     Sum        1117     421    129               338463    77919   12807


     Title: 
     MatStu-ni-001-1x1-11L-Arlxd.in                                             


     bravais-lattice index     =            0
     lattice parameter (alat)  =       1.8897  a.u.
     unit-cell volume          =    1239.2904 (a.u.)^3
     number of atoms/cell      =           11
     number of atomic types    =            1
     number of electrons       =       110.00
     number of Kohn-Sham states=           80
     kinetic-energy cutoff     =      60.0000  Ry
     charge density cutoff     =     640.0000  Ry
     convergence threshold     =      1.0E-06
     mixing beta               =       0.2000
     number of iterations used =            8  plain     mixing
     Exchange-correlation      =  SLA  PW   PBE  PBE ( 1 4 3 4 0)
     EXX-fraction              =        0.00
     nstep                     =           50


     celldm(1)=   1.889726  celldm(2)=   0.000000  celldm(3)=   0.000000
     celldm(4)=   0.000000  celldm(5)=   0.000000  celldm(6)=   0.000000

     crystal axes: (cart. coord. in units of alat)
               a(1) = (   2.490400   0.000000   0.000000 )  
               a(2) = (   0.000000   2.490400   0.000000 )  
               a(3) = (   0.000000   0.000000  29.610000 )  

     reciprocal axes: (cart. coord. in units 2 pi/alat)
               b(1) = (  0.401542  0.000000  0.000000 )  
               b(2) = (  0.000000  0.401542  0.000000 )  
               b(3) = (  0.000000  0.000000  0.033772 )  


     PseudoPot. # 1 for Ni read from file:
     /home/mmc14/pseudo/Ni.pbe-nd-rrkjus.UPF
     MD5 check sum: 8081f0a005c9a5470caab1a58e82ecb2
     Pseudo is Ultrasoft + core correction, Zval = 10.0
     Generated by new atomic code, or converted to UPF format
     Using radial grid of 1203 points,  6 beta functions with: 
                l(1) =   0
                l(2) =   0
                l(3) =   1
                l(4) =   1
                l(5) =   2
                l(6) =   2
     Q(r) pseudized with 0 coefficients 


     atomic species   valence    mass     pseudopotential
        Ni1           10.00    58.69340     Ni( 1.00)

     Starting magnetic structure 
     atomic species   magnetization
        Ni1          0.500

      8 Sym. Ops. (no inversion) found



   Cartesian axes

     site n.     atom                  positions (alat units)
         1           Ni1 tau(   1) = (   0.0000000   0.0000000   0.0000000  )
         2           Ni1 tau(   2) = (   0.0000000   0.0000000   3.5221095  )
         3           Ni1 tau(   3) = (   0.0000000   0.0000000   7.0439229  )
         4           Ni1 tau(   4) = (   0.0000000   0.0000000  10.5660324  )
         5           Ni1 tau(   5) = (   0.0000000   0.0000000  14.0881419  )
         6           Ni1 tau(   6) = (   0.0000000   0.0000000  17.6099553  )
         7           Ni1 tau(   7) = (   1.2452000   1.2452000   1.7609067  )
         8           Ni1 tau(   8) = (   1.2452000   1.2452000   5.2830162  )
         9           Ni1 tau(   9) = (   1.2452000   1.2452000   8.8051257  )
        10           Ni1 tau(  10) = (   1.2452000   1.2452000  12.3269391  )
        11           Ni1 tau(  11) = (   1.2452000   1.2452000  15.8490486  )

     number of k points=    12  Methfessel-Paxton smearing, width (Ry)=  0.0050
                       cart. coord. in units 2pi/alat
        k(    1) = (   0.0000000   0.0000000   0.0000000), wk =   0.0400000
        k(    2) = (   0.0000000   0.0803084   0.0000000), wk =   0.1600000
        k(    3) = (   0.0000000   0.1606168   0.0000000), wk =   0.1600000
        k(    4) = (   0.0803084   0.0803084   0.0000000), wk =   0.1600000
        k(    5) = (   0.0803084   0.1606168   0.0000000), wk =   0.3200000
        k(    6) = (   0.1606168   0.1606168   0.0000000), wk =   0.1600000
        k(    7) = (   0.0000000   0.0000000   0.0000000), wk =   0.0400000
        k(    8) = (   0.0000000   0.0803084   0.0000000), wk =   0.1600000
        k(    9) = (   0.0000000   0.1606168   0.0000000), wk =   0.1600000
        k(   10) = (   0.0803084   0.0803084   0.0000000), wk =   0.1600000
        k(   11) = (   0.0803084   0.1606168   0.0000000), wk =   0.3200000
        k(   12) = (   0.1606168   0.1606168   0.0000000), wk =   0.1600000

     Dense  grid:   338463 G-vectors     FFT dimensions: (  40,  40, 480)

     Smooth grid:    77919 G-vectors     FFT dimensions: (  24,  24, 288)

     Largest allocated arrays     est. size (Mb)     dimensions
        Kohn-Sham Wavefunctions        11.92 Mb     (   9764,   80)
        NL pseudopotentials            29.50 Mb     (   9764,  198)
        Each V/rho on FFT grid         23.44 Mb     ( 768000,   2)
        Each G-vector array             2.58 Mb     ( 338463)
        G-vector shells                 0.16 Mb     (  20664)
     Largest temporary arrays     est. size (Mb)     dimensions
        Auxiliary wavefunctions        47.68 Mb     (   9764,  320)
        Each subspace H/S matrix        1.56 Mb     ( 320, 320)
        Each <psi_i|beta_j> matrix      0.24 Mb     (    198,   80)
        Arrays for rho mixing          93.75 Mb     ( 768000,   8)

     Check: negative/imaginary core charge=   -0.000003    0.000000

     Initial potential from superposition of free atoms

     starting charge  109.99495, renormalised to  110.00000

     negative rho (up, down):  0.297E-05 0.991E-06
     Starting wfc are   66 randomized atomic wfcs

     total cpu time spent up to now is      151.6 secs

     per-process dynamical memory:   209.6 Mb

     Self-consistent Calculation

     iteration #  1     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.00E-02,  avg # of iterations =  6.9

     negative rho (up, down):  0.108E-06 0.000E+00

     total cpu time spent up to now is      911.4 secs

     total energy              =    -942.15333022 Ry
     Harris-Foulkes estimate   =    -943.51632035 Ry
     estimated scf accuracy    <       8.15112342 Ry

     total magnetization       =    20.16 Bohr mag/cell
     absolute magnetization    =    20.17 Bohr mag/cell

     iteration #  2     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  7.41E-03,  avg # of iterations =  3.2

     total cpu time spent up to now is     1471.0 secs

     total energy              =    -938.34918091 Ry
     Harris-Foulkes estimate   =    -948.25483855 Ry
     estimated scf accuracy    <     559.38751065 Ry

     total magnetization       =    20.35 Bohr mag/cell
     absolute magnetization    =    20.61 Bohr mag/cell

     iteration #  3     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  7.41E-03,  avg # of iterations =  2.8

     total cpu time spent up to now is     2048.9 secs

     total energy              =    -941.93493891 Ry
     Harris-Foulkes estimate   =    -943.61231641 Ry
     estimated scf accuracy    <      32.10778805 Ry

     total magnetization       =    15.57 Bohr mag/cell
     absolute magnetization    =    15.82 Bohr mag/cell

     iteration #  4     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  7.41E-03,  avg # of iterations =  1.5

     total cpu time spent up to now is     2582.1 secs

     total energy              =    -942.94730941 Ry
     Harris-Foulkes estimate   =    -943.94422364 Ry
     estimated scf accuracy    <      35.87934715 Ry

     total magnetization       =    15.09 Bohr mag/cell
     absolute magnetization    =    15.49 Bohr mag/cell

     iteration #  5     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  7.41E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     3127.8 secs

     total energy              =    -943.37329949 Ry
     Harris-Foulkes estimate   =    -943.97417736 Ry
     estimated scf accuracy    <      23.31514257 Ry

     total magnetization       =    12.95 Bohr mag/cell
     absolute magnetization    =    13.63 Bohr mag/cell

     iteration #  6     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  7.41E-03,  avg # of iterations =  1.1

     total cpu time spent up to now is     3674.9 secs

     total energy              =    -942.95640809 Ry
     Harris-Foulkes estimate   =    -944.84304478 Ry
     estimated scf accuracy    <     269.18437457 Ry

     total magnetization       =    14.61 Bohr mag/cell
     absolute magnetization    =    14.85 Bohr mag/cell

     iteration #  7     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  7.41E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     4196.7 secs

     total energy              =    -943.78931354 Ry
     Harris-Foulkes estimate   =    -943.82515333 Ry
     estimated scf accuracy    <       4.07999895 Ry

     total magnetization       =    12.97 Bohr mag/cell
     absolute magnetization    =    13.62 Bohr mag/cell

     iteration #  8     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     4744.8 secs

     total energy              =    -944.10285582 Ry
     Harris-Foulkes estimate   =    -944.06001960 Ry
     estimated scf accuracy    <      17.38226135 Ry

     total magnetization       =    12.36 Bohr mag/cell
     absolute magnetization    =    13.26 Bohr mag/cell

     iteration #  9     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-03,  avg # of iterations =  1.4

     total cpu time spent up to now is     5306.6 secs

     total energy              =    -944.55202850 Ry
     Harris-Foulkes estimate   =    -944.57512256 Ry
     estimated scf accuracy    <      29.93765348 Ry

     total magnetization       =    11.35 Bohr mag/cell
     absolute magnetization    =    12.56 Bohr mag/cell

     iteration # 10     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     5828.0 secs

     total energy              =    -944.30294598 Ry
     Harris-Foulkes estimate   =    -944.65076172 Ry
     estimated scf accuracy    <      12.12356327 Ry

     total magnetization       =    10.68 Bohr mag/cell
     absolute magnetization    =    11.80 Bohr mag/cell

     iteration # 11     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     6406.0 secs

     total energy              =    -944.54031399 Ry
     Harris-Foulkes estimate   =    -944.52769199 Ry
     estimated scf accuracy    <       2.89504461 Ry

     total magnetization       =    10.55 Bohr mag/cell
     absolute magnetization    =    11.70 Bohr mag/cell

     iteration # 12     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.63E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     6938.5 secs

     total energy              =    -944.59310722 Ry
     Harris-Foulkes estimate   =    -944.68613566 Ry
     estimated scf accuracy    <       7.20347797 Ry

     total magnetization       =     9.83 Bohr mag/cell
     absolute magnetization    =    11.13 Bohr mag/cell

     iteration # 13     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.63E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     7474.5 secs

     total energy              =    -944.65894504 Ry
     Harris-Foulkes estimate   =    -944.69951734 Ry
     estimated scf accuracy    <       6.63780004 Ry

     total magnetization       =     9.03 Bohr mag/cell
     absolute magnetization    =    10.44 Bohr mag/cell

     iteration # 14     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.63E-03,  avg # of iterations =  1.0

     total cpu time spent up to now is     8008.6 secs

     total energy              =    -944.68762158 Ry
     Harris-Foulkes estimate   =    -944.70092109 Ry
     estimated scf accuracy    <       0.93798857 Ry

     total magnetization       =     8.71 Bohr mag/cell
     absolute magnetization    =    10.08 Bohr mag/cell

     iteration # 15     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  8.53E-04,  avg # of iterations =  1.0

     total cpu time spent up to now is     8549.9 secs

     total energy              =    -944.68455134 Ry
     Harris-Foulkes estimate   =    -944.71834018 Ry
     estimated scf accuracy    <       1.31950470 Ry

     total magnetization       =     8.75 Bohr mag/cell
     absolute magnetization    =    10.01 Bohr mag/cell

     iteration # 16     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  8.53E-04,  avg # of iterations =  1.0

     total cpu time spent up to now is     9094.6 secs

     total energy              =    -944.69225168 Ry
     Harris-Foulkes estimate   =    -944.71114149 Ry
     estimated scf accuracy    <       4.23472117 Ry

     total magnetization       =     8.50 Bohr mag/cell
     absolute magnetization    =     9.76 Bohr mag/cell

     iteration # 17     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  8.53E-04,  avg # of iterations =  1.0

     total cpu time spent up to now is     9629.0 secs

     total energy              =    -944.69745645 Ry
     Harris-Foulkes estimate   =    -944.70739773 Ry
     estimated scf accuracy    <       0.53551206 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.93 Bohr mag/cell

     iteration # 18     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  4.87E-04,  avg # of iterations =  1.0

     total cpu time spent up to now is    10142.4 secs

     total energy              =    -944.70117271 Ry
     Harris-Foulkes estimate   =    -944.70440641 Ry
     estimated scf accuracy    <       0.15475527 Ry

     total magnetization       =     8.63 Bohr mag/cell
     absolute magnetization    =     9.82 Bohr mag/cell

     iteration # 19     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.41E-04,  avg # of iterations =  1.0

     total cpu time spent up to now is    10679.3 secs

     total energy              =    -944.70247460 Ry
     Harris-Foulkes estimate   =    -944.70501374 Ry
     estimated scf accuracy    <       0.11305935 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.93 Bohr mag/cell

     iteration # 20     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.03E-04,  avg # of iterations =  1.0

     total cpu time spent up to now is    11217.7 secs

     total energy              =    -944.70408128 Ry
     Harris-Foulkes estimate   =    -944.70399753 Ry
     estimated scf accuracy    <       0.00923608 Ry

     total magnetization       =     8.68 Bohr mag/cell
     absolute magnetization    =     9.84 Bohr mag/cell

     iteration # 21     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  8.40E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    11730.4 secs

     total energy              =    -944.70419102 Ry
     Harris-Foulkes estimate   =    -944.70464185 Ry
     estimated scf accuracy    <       0.02874533 Ry

     total magnetization       =     8.73 Bohr mag/cell
     absolute magnetization    =     9.87 Bohr mag/cell

     iteration # 22     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  8.40E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    12280.9 secs

     total energy              =    -944.70423483 Ry
     Harris-Foulkes estimate   =    -944.70492039 Ry
     estimated scf accuracy    <       0.03250896 Ry

     total magnetization       =     8.73 Bohr mag/cell
     absolute magnetization    =     9.87 Bohr mag/cell

     iteration # 23     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  8.40E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    12833.2 secs

     total energy              =    -944.70468663 Ry
     Harris-Foulkes estimate   =    -944.70492116 Ry
     estimated scf accuracy    <       0.05579184 Ry

     total magnetization       =     8.73 Bohr mag/cell
     absolute magnetization    =     9.85 Bohr mag/cell

     iteration # 24     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  8.40E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    13352.1 secs

     total energy              =    -944.70529969 Ry
     Harris-Foulkes estimate   =    -944.70501363 Ry
     estimated scf accuracy    <       0.00624067 Ry

     total magnetization       =     8.72 Bohr mag/cell
     absolute magnetization    =     9.84 Bohr mag/cell

     iteration # 25     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.67E-06,  avg # of iterations =  1.4

     total cpu time spent up to now is    13890.5 secs

     total energy              =    -944.70437170 Ry
     Harris-Foulkes estimate   =    -944.70661325 Ry
     estimated scf accuracy    <       0.25978199 Ry

     total magnetization       =     8.73 Bohr mag/cell
     absolute magnetization    =     9.81 Bohr mag/cell

     iteration # 26     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.67E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    14428.5 secs

     total energy              =    -944.70504298 Ry
     Harris-Foulkes estimate   =    -944.70575275 Ry
     estimated scf accuracy    <       0.02035480 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.82 Bohr mag/cell

     iteration # 27     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.67E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    14978.9 secs

     total energy              =    -944.70520574 Ry
     Harris-Foulkes estimate   =    -944.70593511 Ry
     estimated scf accuracy    <       0.23122137 Ry

     total magnetization       =     8.72 Bohr mag/cell
     absolute magnetization    =     9.82 Bohr mag/cell

     iteration # 28     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.67E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    15500.9 secs

     total energy              =    -944.70522533 Ry
     Harris-Foulkes estimate   =    -944.70646221 Ry
     estimated scf accuracy    <       0.06134773 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.81 Bohr mag/cell

     iteration # 29     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.67E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    16011.9 secs

     total energy              =    -944.70532059 Ry
     Harris-Foulkes estimate   =    -944.70642648 Ry
     estimated scf accuracy    <       0.03465493 Ry

     total magnetization       =     8.75 Bohr mag/cell
     absolute magnetization    =     9.80 Bohr mag/cell

     iteration # 30     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.67E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    16559.0 secs

     total energy              =    -944.70592988 Ry
     Harris-Foulkes estimate   =    -944.70588111 Ry
     estimated scf accuracy    <       0.00407723 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.81 Bohr mag/cell

     iteration # 31     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    17104.5 secs

     total energy              =    -944.70600382 Ry
     Harris-Foulkes estimate   =    -944.70619218 Ry
     estimated scf accuracy    <       0.01379314 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.79 Bohr mag/cell

     iteration # 32     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    17614.0 secs

     total energy              =    -944.70564488 Ry
     Harris-Foulkes estimate   =    -944.70626810 Ry
     estimated scf accuracy    <       0.00991177 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.78 Bohr mag/cell

     iteration # 33     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    18160.7 secs

     total energy              =    -944.70570173 Ry
     Harris-Foulkes estimate   =    -944.70617915 Ry
     estimated scf accuracy    <       0.08591740 Ry

     total magnetization       =     8.72 Bohr mag/cell
     absolute magnetization    =     9.79 Bohr mag/cell

     iteration # 34     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    18716.0 secs

     total energy              =    -944.70617788 Ry
     Harris-Foulkes estimate   =    -944.70606880 Ry
     estimated scf accuracy    <       0.00627911 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.79 Bohr mag/cell

     iteration # 35     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    19261.1 secs

     total energy              =    -944.70600866 Ry
     Harris-Foulkes estimate   =    -944.70636662 Ry
     estimated scf accuracy    <       0.02064512 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.77 Bohr mag/cell

     iteration # 36     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    19830.9 secs

     total energy              =    -944.70610700 Ry
     Harris-Foulkes estimate   =    -944.70618533 Ry
     estimated scf accuracy    <       0.00556809 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.78 Bohr mag/cell

     iteration # 37     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    20359.5 secs

     total energy              =    -944.70618050 Ry
     Harris-Foulkes estimate   =    -944.70625565 Ry
     estimated scf accuracy    <       0.03545132 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.78 Bohr mag/cell

     iteration # 38     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.71E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    20886.0 secs

     total energy              =    -944.70626124 Ry
     Harris-Foulkes estimate   =    -944.70632300 Ry
     estimated scf accuracy    <       0.00286016 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.77 Bohr mag/cell

     iteration # 39     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.60E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    21416.3 secs

     total energy              =    -944.70621888 Ry
     Harris-Foulkes estimate   =    -944.70636088 Ry
     estimated scf accuracy    <       0.00493982 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.76 Bohr mag/cell

     iteration # 40     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.60E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    21961.4 secs

     total energy              =    -944.70628842 Ry
     Harris-Foulkes estimate   =    -944.70634130 Ry
     estimated scf accuracy    <       0.00214868 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.76 Bohr mag/cell

     iteration # 41     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.95E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    22498.4 secs

     total energy              =    -944.70634989 Ry
     Harris-Foulkes estimate   =    -944.70636848 Ry
     estimated scf accuracy    <       0.00304026 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.76 Bohr mag/cell

     iteration # 42     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.95E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    23034.7 secs

     total energy              =    -944.70631494 Ry
     Harris-Foulkes estimate   =    -944.70640709 Ry
     estimated scf accuracy    <       0.00138479 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.75 Bohr mag/cell

     iteration # 43     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.26E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    23552.2 secs

     total energy              =    -944.70614360 Ry
     Harris-Foulkes estimate   =    -944.70656172 Ry
     estimated scf accuracy    <       0.05757312 Ry

     total magnetization       =     8.75 Bohr mag/cell
     absolute magnetization    =     9.76 Bohr mag/cell

     iteration # 44     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.26E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    24103.4 secs

     total energy              =    -944.70637369 Ry
     Harris-Foulkes estimate   =    -944.70638541 Ry
     estimated scf accuracy    <       0.00404534 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.76 Bohr mag/cell

     iteration # 45     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.26E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    24658.7 secs

     total energy              =    -944.70632555 Ry
     Harris-Foulkes estimate   =    -944.70643568 Ry
     estimated scf accuracy    <       0.00337607 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.74 Bohr mag/cell

     iteration # 46     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.26E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    25163.4 secs

     total energy              =    -944.70636374 Ry
     Harris-Foulkes estimate   =    -944.70638529 Ry
     estimated scf accuracy    <       0.00606054 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.75 Bohr mag/cell

     iteration # 47     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.26E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    25711.6 secs

     total energy              =    -944.70636806 Ry
     Harris-Foulkes estimate   =    -944.70641570 Ry
     estimated scf accuracy    <       0.00860253 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.75 Bohr mag/cell

     iteration # 48     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.26E-06,  avg # of iterations =  1.0

     total cpu time spent up to now is    26250.7 secs

     total energy              =    -944.70640399 Ry
     Harris-Foulkes estimate   =    -944.70640735 Ry
     estimated scf accuracy    <       0.00071680 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.74 Bohr mag/cell

     iteration # 49     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  6.52E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    26776.9 secs

     total energy              =    -944.70641404 Ry
     Harris-Foulkes estimate   =    -944.70641585 Ry
     estimated scf accuracy    <       0.00033819 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.74 Bohr mag/cell

     iteration # 50     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.07E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    27313.1 secs

     total energy              =    -944.70641473 Ry
     Harris-Foulkes estimate   =    -944.70642701 Ry
     estimated scf accuracy    <       0.00026844 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.74 Bohr mag/cell

     iteration # 51     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.44E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    27868.7 secs

     total energy              =    -944.70641561 Ry
     Harris-Foulkes estimate   =    -944.70643473 Ry
     estimated scf accuracy    <       0.00131505 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.74 Bohr mag/cell

     iteration # 52     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.44E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    28394.5 secs

     total energy              =    -944.70640563 Ry
     Harris-Foulkes estimate   =    -944.70643177 Ry
     estimated scf accuracy    <       0.00057356 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.74 Bohr mag/cell

     iteration # 53     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.44E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    28936.3 secs

     total energy              =    -944.70627355 Ry
     Harris-Foulkes estimate   =    -944.70657211 Ry
     estimated scf accuracy    <       0.04352339 Ry

     total magnetization       =     8.73 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 54     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.44E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    29474.3 secs

     total energy              =    -944.70643030 Ry
     Harris-Foulkes estimate   =    -944.70644296 Ry
     estimated scf accuracy    <       0.00099986 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 55     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.44E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    30004.0 secs

     total energy              =    -944.70642683 Ry
     Harris-Foulkes estimate   =    -944.70644225 Ry
     estimated scf accuracy    <       0.00018207 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 56     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.66E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    30542.4 secs

     total energy              =    -944.70637251 Ry
     Harris-Foulkes estimate   =    -944.70649657 Ry
     estimated scf accuracy    <       0.01878285 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 57     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.66E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    31068.5 secs

     total energy              =    -944.70643025 Ry
     Harris-Foulkes estimate   =    -944.70644430 Ry
     estimated scf accuracy    <       0.00265106 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 58     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.66E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    31615.2 secs

     total energy              =    -944.70643987 Ry
     Harris-Foulkes estimate   =    -944.70644241 Ry
     estimated scf accuracy    <       0.00025955 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 59     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.66E-07,  avg # of iterations =  1.0

     total cpu time spent up to now is    32218.9 secs

     total energy              =    -944.70644376 Ry
     Harris-Foulkes estimate   =    -944.70644340 Ry
     estimated scf accuracy    <       0.00005774 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 60     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.25E-08,  avg # of iterations =  1.0

     total cpu time spent up to now is    32744.8 secs

     total energy              =    -944.70644397 Ry
     Harris-Foulkes estimate   =    -944.70644647 Ry
     estimated scf accuracy    <       0.00009560 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 61     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.25E-08,  avg # of iterations =  1.0

     total cpu time spent up to now is    33266.2 secs

     total energy              =    -944.70644233 Ry
     Harris-Foulkes estimate   =    -944.70644812 Ry
     estimated scf accuracy    <       0.00028987 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 62     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.25E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.147E-07 0.441E-09

     total cpu time spent up to now is    33806.5 secs

     total energy              =    -944.70645148 Ry
     Harris-Foulkes estimate   =    -944.70644596 Ry
     estimated scf accuracy    <       0.00003992 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.73 Bohr mag/cell

     iteration # 63     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     total cpu time spent up to now is    34334.9 secs

     total energy              =    -944.70644191 Ry
     Harris-Foulkes estimate   =    -944.70645762 Ry
     estimated scf accuracy    <       0.00152471 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 64     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     total cpu time spent up to now is    34887.6 secs

     total energy              =    -944.70644787 Ry
     Harris-Foulkes estimate   =    -944.70645005 Ry
     estimated scf accuracy    <       0.00022702 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 65     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.805E-07 0.918E-08

     total cpu time spent up to now is    35407.6 secs

     total energy              =    -944.70645380 Ry
     Harris-Foulkes estimate   =    -944.70645033 Ry
     estimated scf accuracy    <       0.00004177 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 66     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     total cpu time spent up to now is    35939.6 secs

     total energy              =    -944.70644307 Ry
     Harris-Foulkes estimate   =    -944.70646077 Ry
     estimated scf accuracy    <       0.00162449 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 67     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     total cpu time spent up to now is    36493.9 secs

     total energy              =    -944.70644634 Ry
     Harris-Foulkes estimate   =    -944.70645571 Ry
     estimated scf accuracy    <       0.00177799 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 68     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.204E-07 0.969E-09

     total cpu time spent up to now is    37027.5 secs

     total energy              =    -944.70645112 Ry
     Harris-Foulkes estimate   =    -944.70645322 Ry
     estimated scf accuracy    <       0.00014837 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 69     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.266E-07 0.168E-08

     total cpu time spent up to now is    37553.2 secs

     total energy              =    -944.70645254 Ry
     Harris-Foulkes estimate   =    -944.70645398 Ry
     estimated scf accuracy    <       0.00005789 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 70     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.382E-07 0.310E-08

     total cpu time spent up to now is    38104.9 secs

     total energy              =    -944.70645332 Ry
     Harris-Foulkes estimate   =    -944.70645460 Ry
     estimated scf accuracy    <       0.00006552 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 71     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.264E-07 0.166E-08

     total cpu time spent up to now is    38657.6 secs

     total energy              =    -944.70645163 Ry
     Harris-Foulkes estimate   =    -944.70645611 Ry
     estimated scf accuracy    <       0.00017815 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 72     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.63E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.519E-07 0.478E-08

     total cpu time spent up to now is    39169.6 secs

     total energy              =    -944.70645477 Ry
     Harris-Foulkes estimate   =    -944.70645410 Ry
     estimated scf accuracy    <       0.00003063 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 73     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.78E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.514E-07 0.472E-08

     total cpu time spent up to now is    39705.7 secs

     total energy              =    -944.70645336 Ry
     Harris-Foulkes estimate   =    -944.70645652 Ry
     estimated scf accuracy    <       0.00036319 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 74     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.78E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.482E-07 0.426E-08

     total cpu time spent up to now is    40228.9 secs

     total energy              =    -944.70645452 Ry
     Harris-Foulkes estimate   =    -944.70645560 Ry
     estimated scf accuracy    <       0.00010731 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 75     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  2.78E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.107E-06 0.144E-07

     total cpu time spent up to now is    40766.6 secs

     total energy              =    -944.70645645 Ry
     Harris-Foulkes estimate   =    -944.70645522 Ry
     estimated scf accuracy    <       0.00001463 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 76     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.560E-07 0.539E-08

     total cpu time spent up to now is    41326.5 secs

     total energy              =    -944.70645416 Ry
     Harris-Foulkes estimate   =    -944.70645699 Ry
     estimated scf accuracy    <       0.00007382 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 77     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.880E-07 0.106E-07

     total cpu time spent up to now is    41757.9 secs

     total energy              =    -944.70645303 Ry
     Harris-Foulkes estimate   =    -944.70645854 Ry
     estimated scf accuracy    <       0.00156031 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 78     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.102E-06 0.134E-07

     total cpu time spent up to now is    42212.5 secs

     total energy              =    -944.70645548 Ry
     Harris-Foulkes estimate   =    -944.70645745 Ry
     estimated scf accuracy    <       0.00012175 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 79     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.140E-06 0.218E-07

     total cpu time spent up to now is    42644.6 secs

     total energy              =    -944.70645691 Ry
     Harris-Foulkes estimate   =    -944.70645691 Ry
     estimated scf accuracy    <       0.00001815 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.72 Bohr mag/cell

     iteration # 80     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.148E-06 0.239E-07

     total cpu time spent up to now is    43050.7 secs

     total energy              =    -944.70645688 Ry
     Harris-Foulkes estimate   =    -944.70645767 Ry
     estimated scf accuracy    <       0.00003065 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 81     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.117E-06 0.165E-07

     total cpu time spent up to now is    43455.6 secs

     total energy              =    -944.70645578 Ry
     Harris-Foulkes estimate   =    -944.70645814 Ry
     estimated scf accuracy    <       0.00007918 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 82     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.183E-06 0.341E-07

     total cpu time spent up to now is    43911.8 secs

     total energy              =    -944.70645719 Ry
     Harris-Foulkes estimate   =    -944.70645749 Ry
     estimated scf accuracy    <       0.00004077 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 83     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.148E-06 0.240E-07

     total cpu time spent up to now is    44333.1 secs

     total energy              =    -944.70645682 Ry
     Harris-Foulkes estimate   =    -944.70645817 Ry
     estimated scf accuracy    <       0.00011670 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 84     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.134E-06 0.204E-07

     total cpu time spent up to now is    44744.7 secs

     total energy              =    -944.70645685 Ry
     Harris-Foulkes estimate   =    -944.70645769 Ry
     estimated scf accuracy    <       0.00005316 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 85     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.33E-08,  avg # of iterations =  1.0

     negative rho (up, down):  0.173E-06 0.309E-07

     total cpu time spent up to now is    45175.2 secs

     total energy              =    -944.70645765 Ry
     Harris-Foulkes estimate   =    -944.70645733 Ry
     estimated scf accuracy    <       0.00000592 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 86     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  5.38E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.172E-06 0.307E-07

     total cpu time spent up to now is    45571.4 secs

     total energy              =    -944.70645752 Ry
     Harris-Foulkes estimate   =    -944.70645778 Ry
     estimated scf accuracy    <       0.00000537 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 87     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  4.88E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.173E-06 0.309E-07

     total cpu time spent up to now is    46000.3 secs

     total energy              =    -944.70645585 Ry
     Harris-Foulkes estimate   =    -944.70645958 Ry
     estimated scf accuracy    <       0.00096231 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 88     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  4.88E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.177E-06 0.321E-07

     total cpu time spent up to now is    46465.5 secs

     total energy              =    -944.70645737 Ry
     Harris-Foulkes estimate   =    -944.70645812 Ry
     estimated scf accuracy    <       0.00003749 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 89     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  4.88E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.192E-06 0.367E-07

     total cpu time spent up to now is    46862.9 secs

     total energy              =    -944.70645790 Ry
     Harris-Foulkes estimate   =    -944.70645784 Ry
     estimated scf accuracy    <       0.00000342 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 90     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.11E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.216E-06 0.441E-07

     total cpu time spent up to now is    47279.4 secs

     total energy              =    -944.70645804 Ry
     Harris-Foulkes estimate   =    -944.70645804 Ry
     estimated scf accuracy    <       0.00000469 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 91     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.11E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.216E-06 0.439E-07

     total cpu time spent up to now is    47717.9 secs

     total energy              =    -944.70645793 Ry
     Harris-Foulkes estimate   =    -944.70645829 Ry
     estimated scf accuracy    <       0.00001332 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 92     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.11E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.208E-06 0.413E-07

     total cpu time spent up to now is    48173.7 secs

     total energy              =    -944.70645787 Ry
     Harris-Foulkes estimate   =    -944.70645835 Ry
     estimated scf accuracy    <       0.00001934 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 93     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.11E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.221E-06 0.455E-07

     total cpu time spent up to now is    48594.7 secs

     total energy              =    -944.70645801 Ry
     Harris-Foulkes estimate   =    -944.70645823 Ry
     estimated scf accuracy    <       0.00003458 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 94     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.11E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.202E-06 0.395E-07

     total cpu time spent up to now is    49010.2 secs

     total energy              =    -944.70645790 Ry
     Harris-Foulkes estimate   =    -944.70645830 Ry
     estimated scf accuracy    <       0.00001959 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 95     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.11E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.223E-06 0.462E-07

     total cpu time spent up to now is    49418.1 secs

     total energy              =    -944.70645814 Ry
     Harris-Foulkes estimate   =    -944.70645814 Ry
     estimated scf accuracy    <       0.00000690 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 96     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  3.11E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.243E-06 0.527E-07

     total cpu time spent up to now is    49861.8 secs

     total energy              =    -944.70645829 Ry
     Harris-Foulkes estimate   =    -944.70645824 Ry
     estimated scf accuracy    <       0.00000140 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 97     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.27E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.241E-06 0.521E-07

     total cpu time spent up to now is    50305.4 secs

     total energy              =    -944.70645782 Ry
     Harris-Foulkes estimate   =    -944.70645884 Ry
     estimated scf accuracy    <       0.00025450 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 98     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.27E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.223E-06 0.463E-07

     total cpu time spent up to now is    50705.1 secs

     total energy              =    -944.70645811 Ry
     Harris-Foulkes estimate   =    -944.70645843 Ry
     estimated scf accuracy    <       0.00001046 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration # 99     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.27E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.235E-06 0.502E-07

     total cpu time spent up to now is    51156.6 secs

     total energy              =    -944.70645831 Ry
     Harris-Foulkes estimate   =    -944.70645826 Ry
     estimated scf accuracy    <       0.00000118 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     iteration #100     ecut=    60.00 Ry     beta=0.20
     Davidson diagonalization with overlap
     ethr =  1.07E-09,  avg # of iterations =  1.0

     negative rho (up, down):  0.239E-06 0.515E-07

     total cpu time spent up to now is    51612.3 secs

     total energy              =    -944.70645833 Ry
     Harris-Foulkes estimate   =    -944.70645835 Ry
     estimated scf accuracy    <       0.00000118 Ry

     total magnetization       =     8.74 Bohr mag/cell
     absolute magnetization    =     9.71 Bohr mag/cell

     End of self-consistent calculation

     convergence NOT achieved after 100 iterations: stopping

     Writing output data file ni-100-1x1-11L-allrlxd.save

     init_run     :    145.93s CPU    151.42s WALL (       1 calls)
     electrons    :  42258.93s CPU  51460.76s WALL (       1 calls)

     Called by init_run:
     wfcinit      :    111.85s CPU    116.92s WALL (       1 calls)
     potinit      :      6.19s CPU      6.32s WALL (       1 calls)

     Called by electrons:
     c_bands      :  28885.93s CPU  35273.54s WALL (     100 calls)
     sum_band     :   8551.87s CPU  10340.49s WALL (     100 calls)
     v_of_rho     :    491.53s CPU    604.32s WALL (     101 calls)
     newd         :   4241.28s CPU   5126.91s WALL (     101 calls)
     mix_rho      :     68.27s CPU     80.67s WALL (     100 calls)

     Called by c_bands:
     init_us_2    :    125.13s CPU    151.80s WALL (    2412 calls)
     cegterg      :  28363.86s CPU  34579.16s WALL (    1200 calls)

     Called by *egterg:
     h_psi        :  15149.85s CPU  18325.37s WALL (    2549 calls)
     s_psi        :   4307.12s CPU   5219.91s WALL (    2549 calls)
     g_psi        :     26.87s CPU     32.74s WALL (    1337 calls)
     cdiaghg      :     91.72s CPU    111.85s WALL (    2537 calls)

     Called by h_psi:
     add_vuspsi   :   4303.53s CPU   5229.80s WALL (    2549 calls)

     General routines
     calbec       :   6373.89s CPU   7716.91s WALL (    3749 calls)
     fft          :    215.24s CPU    257.20s WALL (    3125 calls)
     ffts         :      5.83s CPU      7.12s WALL (     402 calls)
     fftw         :   4350.71s CPU   5212.75s WALL (  484900 calls)
     interpolate  :     44.58s CPU     52.87s WALL (     402 calls)
     davcio       :      0.12s CPU     81.27s WALL (    3612 calls)


     PWSCF        :    11h46m CPU       14h20m WALL


   This run was terminated on:   8:53: 2  30Oct2014            

=------------------------------------------------------------------------------=
   JOB DONE.
=------------------------------------------------------------------------------=
STOP 1
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