[Pw_forum] Having problem with Total energy in Band structure calculation

Alhassan Shuaibu alhazikara at gmail.com
Sun Jan 12 07:19:56 CET 2014


Hello
I am trying to do band structure calculations for Ternary Bi2Te2S.But I am
getting a positive TOTAL energy . I have checked my crystal structure with
Xcrysden, looks
okay to me. please is this related to my generated coordinate?
my INPUT FILE
&CONTROL
    calculation='scf'
    restart_mode='from_scratch',
    prefix='Bi2Te2SRH_exc1',
    tstress = .true.
    tprnfor = .true.
    pseudo_dir ='/home/alhas/Alhas/espresso-5.0.2/pseudo/' ,
    outdir='/home/alhas/Alhas/espresso-5.0.2/bin/' ,
 /
 &SYSTEM
                    ibrav =  5,
                     a = 10.931,
                     cosab = 0.922901387,
                     nat = 5,
                     ntyp = 3,
                     ecutwfc = 20 ,

/
 &ELECTRONS
               conv_thr = 1.0d-8
                startingwfc = 'atomic' ,
                 mixing_mode = 'plain' ,
                 mixing_beta = 0.7 ,

/

ATOMIC_SPECIES
Bi 208.9804 Bi.pbe-hgh.UPF
Te 127.6    Te.pbe-hgh.UPF
S  32.065   S.pbe-hgh.UPF
ATOMIC_POSITIONS (angstrom)
  Bi      0.38788600000000   0.38788600000000   0.38788600000000
  Bi      0.61211400000000   0.61211400000000   0.61211400000000
  Te      0.77733500000000   0.77733500000000   0.77733500000000
  Te      0.22266500000000   0.22266500000000   0.22266500000000
  S       0.00000000000000   0.00000000000000   0.00000000000000
K_POINTS (automatic)
 7 7 1 0 0 0
and the OUT PUT FILE LOOK LIKE

     Program PWSCF v.5.0.2 (svn rev. 9392) starts on 12Jan2014 at 11:44:27

     This program is part of the open-source Quantum ESPRESSO suite
     for quantum simulation of materials; please cite
         "P. Giannozzi et al., J. Phys.:Condens. Matter 21 395502 (2009);
          URL http://www.quantum-espresso.org",
     in publications or presentations arising from this work. More details
at
     http://www.quantum-espresso.org/quote.php

     Serial version

     Current dimensions of program PWSCF are:
     Max number of different atomic species (ntypx) = 10
     Max number of k-points (npk) =  40000
     Max angular momentum in pseudopotentials (lmaxx) =  3
     Waiting for input...
     Reading input from standard input

     G-vector sticks info
     --------------------
     sticks:   dense  smooth     PW     G-vecs:    dense   smooth      PW
     Sum        1051    1051    343                13881    13881    2655



     bravais-lattice index     =            5
     lattice parameter (alat)  =      20.6566  a.u.
     unit-cell volume          =    1146.3712 (a.u.)^3
     number of atoms/cell      =            5
     number of atomic types    =            3
     number of electrons       =        28.00
     number of Kohn-Sham states=           14
     kinetic-energy cutoff     =      20.0000  Ry
     charge density cutoff     =      80.0000  Ry
     convergence threshold     =      1.0E-08
     mixing beta               =       0.7000
     number of iterations used =            8  plain     mixing
     Exchange-correlation      = SLA-PW-PBX-PBC ( 1 4 3 4 0)
     EXX-fraction              =        0.00

     celldm(1)=  20.656596  celldm(2)=   0.000000  celldm(3)=   0.000000
     celldm(4)=   0.922901  celldm(5)=   0.000000  celldm(6)=   0.000000

     crystal axes: (cart. coord. in units of alat)
               a(1) = (   0.196340  -0.113357   0.973961 )
               a(2) = (   0.000000   0.226714   0.973961 )
               a(3) = (  -0.196340  -0.113357   0.973961 )

     reciprocal axes: (cart. coord. in units 2 pi/alat)
               b(1) = (  2.546606 -1.470284  0.342245 )
               b(2) = (  0.000000  2.940567  0.342245 )
               b(3) = ( -2.546606 -1.470284  0.342245 )


     PseudoPot. # 1 for Bi read from file:
     /home/alhas/Alhas/espresso-5.
0.2/pseudo/Bi.pbe-hgh.UPF
     MD5 check sum: fa1107c6db4de18592e3d11c2e594848
     Pseudo is Norm-conserving, Zval =  5.0
     Generated in analytical, separable form
     Using radial grid of 1283 points,  6 beta functions with:
                l(1) =   0
                l(2) =   0
                l(3) =   0
                l(4) =   1
                l(5) =   1
                l(6) =   2

     PseudoPot. # 2 for Te read from file:
     /home/alhas/Alhas/espresso-5.0.2/pseudo/Te.pbe-hgh.UPF
     MD5 check sum: fc0a86712a641bf9485b17524305deab
     Pseudo is Norm-conserving, Zval =  6.0
     Generated in analytical, separable form
     Using radial grid of 1245 points,  6 beta functions with:
                l(1) =   0
                l(2) =   0
                l(3) =   0
                l(4) =   1
                l(5) =   1
                l(6) =   2

     PseudoPot. # 3 for  S read from file:
     /home/alhas/Alhas/espresso-5.0.2/pseudo/S.pbe-hgh.UPF
     MD5 check sum: f6198a88890a2400cb0813e3da6c62fb
     Pseudo is Norm-conserving, Zval =  6.0
     Generated in analytical, separable form
     Using radial grid of 1151 points,  3 beta functions with:
                l(1) =   0
                l(2) =   0
                l(3) =   1

     atomic species   valence    mass     pseudopotential
        Bi             5.00   208.98040     Bi( 1.00)
        Te             6.00   127.60000     Te( 1.00)
        S              6.00    32.06500      S( 1.00)

     No symmetry found



   Cartesian axes

     site n.     atom                  positions (alat units)
         1           Bi  tau(   1) = (   0.0354850   0.0354850   0.0354850
)
         2           Bi  tau(   2) = (   0.0559980   0.0559980   0.0559980
)
         3           Te  tau(   3) = (   0.0711129   0.0711129   0.0711129
)
         4           Te  tau(   4) = (   0.0203700   0.0203700   0.0203700
)
         5           S   tau(   5) = (   0.0000000   0.0000000   0.0000000
)

     number of k points=    64
                       cart. coord. in units 2pi/alat
        k(    1) = (   0.0000000   0.0000000   0.0000000), wk =   0.0408163
        k(    2) = (   0.0000000   0.4200810   0.0488921), wk =   0.0544218
        k(    3) = (   0.0000000   0.8401620   0.0977843), wk =   0.0544218
        k(    4) = (   0.0000000   1.2602430   0.1466764), wk =   0.0544218
        k(    5) = (   0.3638008   0.2100405   0.0977843), wk =   0.0272109
        k(    6) = (   0.3638008   0.6301215   0.1466764), wk =   0.0272109
        k(    7) = (   0.3638008   1.0502025   0.1955685), wk =   0.0272109
        k(    8) = (   0.3638008  -1.4702835  -0.0977843), wk =   0.0272109
        k(    9) = (   0.3638008  -1.0502025  -0.0488921), wk =   0.0272109
        k(   10) = (   0.3638008  -0.6301215  -0.0000000), wk =   0.0272109
        k(   11) = (   0.7276016   0.4200810   0.1955685), wk =   0.0272109
        k(   12) = (   0.7276016   0.8401620   0.2444606), wk =   0.0272109
        k(   13) = (   0.7276016  -1.6803240  -0.0488921), wk =   0.0272109
        k(   14) = (   0.7276016  -1.2602430  -0.0000000), wk =   0.0272109
        k(   15) = (   1.0914025   0.6301215   0.2933528), wk =   0.0272109
        k(   16) = (   1.0914025  -1.8903645  -0.0000000), wk =   0.0272109
        k(   17) = (  -0.3638008  -0.2100405   0.0488921), wk =   0.0544218
        k(   18) = (   0.3638008  -0.2100405   0.0488921), wk =   0.0544218
        k(   19) = (  -0.7276016  -0.4200810   0.0977843), wk =   0.0544218
        k(   20) = (   0.7276016  -0.4200810   0.0977843), wk =   0.0544218
        k(   21) = (  -1.0914025  -0.6301215   0.1466764), wk =   0.0544218
        k(   22) = (   1.0914025  -0.6301215   0.1466764), wk =   0.0544218
        k(   23) = (   0.3638008  -0.2100405  -0.0977843), wk =   0.0272109
        k(   24) = (   0.0000000  -0.4200810   0.0977843), wk =   0.0272109
        k(   25) = (   0.3638008  -0.6301215  -0.1466764), wk =   0.0272109
        k(   26) = (  -0.7276016   0.0000000   0.1466764), wk =   0.0272109
        k(   27) = (   0.3638008  -0.6301215   0.1466764), wk =   0.0272109
        k(   28) = (  -0.7276016  -0.0000000  -0.1466764), wk =   0.0272109
        k(   29) = (   0.3638008   0.6301215  -0.1466764), wk =   0.0272109
        k(   30) = (   0.3638008  -1.0502025  -0.1955685), wk =   0.0272109
        k(   31) = (  -1.0914025  -0.2100405   0.1955685), wk =   0.0272109
        k(   32) = (   0.7276016  -0.8401620   0.1955685), wk =   0.0272109
        k(   33) = (  -1.0914025   0.2100405  -0.1955685), wk =   0.0272109
        k(   34) = (   0.7276016   0.8401620  -0.1955685), wk =   0.0272109
        k(   35) = (   0.3638008   1.4702835   0.0977843), wk =   0.0272109
        k(   36) = (   1.0914025   1.0502025  -0.0977843), wk =   0.0272109
        k(   37) = (  -1.4552033   0.4200810  -0.0977843), wk =   0.0272109
        k(   38) = (   1.0914025  -1.0502025   0.0977843), wk =   0.0272109
        k(   39) = (  -1.4552033  -0.4200810   0.0977843), wk =   0.0272109
        k(   40) = (   0.3638008   1.0502025   0.0488921), wk =   0.0272109
        k(   41) = (   0.7276016   0.8401620  -0.0488921), wk =   0.0272109
        k(   42) = (  -1.0914025   0.2100405  -0.0488921), wk =   0.0272109
        k(   43) = (   0.7276016  -0.8401620   0.0488921), wk =   0.0272109
        k(   44) = (  -1.0914025  -0.2100405   0.0488921), wk =   0.0272109
        k(   45) = (   0.3638008   0.6301215   0.0000000), wk =   0.0272109
        k(   46) = (  -0.7276016   0.0000000  -0.0000000), wk =   0.0272109
        k(   47) = (   0.7276016  -0.4200810  -0.1955685), wk =   0.0272109
        k(   48) = (   0.0000000  -0.8401620   0.1955685), wk =   0.0272109
        k(   49) = (   0.7276016  -0.8401620  -0.2444606), wk =   0.0272109
        k(   50) = (  -1.0914025   0.2100405   0.2444606), wk =   0.0272109
        k(   51) = (   0.3638008  -1.0502025   0.2444606), wk =   0.0272109
        k(   52) = (  -1.0914025  -0.2100405  -0.2444606), wk =   0.0272109
        k(   53) = (   0.3638008   1.0502025  -0.2444606), wk =   0.0272109
        k(   54) = (   0.7276016   1.6803240   0.0488921), wk =   0.0272109
        k(   55) = (   1.0914025   1.4702835  -0.0488921), wk =   0.0272109
        k(   56) = (  -1.8190041   0.2100405  -0.0488921), wk =   0.0272109
        k(   57) = (   1.0914025  -1.4702835   0.0488921), wk =   0.0272109
        k(   58) = (  -1.8190041  -0.2100405   0.0488921), wk =   0.0272109
        k(   59) = (   0.7276016   1.2602430   0.0000000), wk =   0.0272109
        k(   60) = (  -1.4552033  -0.0000000  -0.0000000), wk =   0.0272109
        k(   61) = (   1.0914025  -0.6301215  -0.2933528), wk =   0.0272109
        k(   62) = (   0.0000000  -1.2602430   0.2933528), wk =   0.0272109
        k(   63) = (   1.0914025   1.8903645   0.0000000), wk =   0.0272109
        k(   64) = (  -2.1828049   0.0000000  -0.0000000), wk =   0.0272109

     Dense  grid:    13881 G-vectors     FFT dimensions: (  60,  60,  60)

     Largest allocated arrays     est. size (Mb)     dimensions
        Kohn-Sham Wavefunctions         0.37 Mb     (   1740,   14)
        NL pseudopotentials             1.62 Mb     (   1740,   61)
        Each V/rho on FFT grid          3.30 Mb     ( 216000)
        Each G-vector array             0.11 Mb     (  13881)
        G-vector shells                 0.01 Mb     (   1172)
     Largest temporary arrays     est. size (Mb)     dimensions
        Auxiliary wavefunctions         1.49 Mb     (   1740,   56)
        Each subspace H/S matrix        0.05 Mb     (  56,  56)
        Each <psi_i|beta_j> matrix      0.01 Mb     (     61,   14)
        Arrays for rho mixing          26.37 Mb     ( 216000,   8)

     Initial potential from superposition of free atoms
     Check: negative starting charge=   -0.002796

     starting charge   22.99993, renormalised to   28.00000

     negative rho (up, down):  0.340E-02 0.000E+00
     Starting wfc are   45 randomized atomic wfcs

     total cpu time spent up to now is       31.9 secs

     per-process dynamical memory:    26.9 Mb

     Self-consistent Calculation

     iteration #  1     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.00E-02,  avg # of iterations =  4.1

     total cpu time spent up to now is       76.2 secs

     total energy              =     310.63910576 Ry
     Harris-Foulkes estimate   =     306.54374577 Ry
     estimated scf accuracy    <       5.58671276 Ry

     iteration #  2     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.00E-02,  avg # of iterations =  9.0

     total cpu time spent up to now is      126.8 secs

     total energy              =     311.43836344 Ry
     Harris-Foulkes estimate   =     304.50821707 Ry
     estimated scf accuracy    <      17.94894679 Ry

     iteration #  3     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.00E-02,  avg # of iterations =  4.6

     total cpu time spent up to now is      173.6 secs

     total energy              =     308.51687266 Ry
     Harris-Foulkes estimate   =     307.40277691 Ry
     estimated scf accuracy    <       3.83259108 Ry

     iteration #  4     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.00E-02,  avg # of iterations =  4.3

     total cpu time spent up to now is      206.1 secs

     total energy              =     308.15523825 Ry
     Harris-Foulkes estimate   =     307.87303161 Ry
     estimated scf accuracy    <       0.83529219 Ry

     iteration #  5     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  2.98E-03,  avg # of iterations =  4.3

     total cpu time spent up to now is      238.2 secs

     total energy              =     308.03666033 Ry
     Harris-Foulkes estimate   =     307.98197122 Ry
     estimated scf accuracy    <       0.12237080 Ry

     iteration #  6     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.37E-04,  avg # of iterations =  5.3

     total cpu time spent up to now is      275.1 secs

     total energy              =     308.00201433 Ry
     Harris-Foulkes estimate   =     307.99739432 Ry
     estimated scf accuracy    <       0.01107009 Ry

     iteration #  7     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  3.95E-05,  avg # of iterations =  7.7

     total cpu time spent up to now is      317.3 secs

     total energy              =     307.99638800 Ry
     Harris-Foulkes estimate   =     307.99413520 Ry
     estimated scf accuracy    <       0.00743993 Ry

     iteration #  8     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  2.66E-05,  avg # of iterations =  4.4

     total cpu time spent up to now is      346.7 secs

     total energy              =     307.99591142 Ry
     Harris-Foulkes estimate   =     307.99538810 Ry
     estimated scf accuracy    <       0.00154320 Ry

     iteration #  9     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  5.51E-06,  avg # of iterations =  6.7

     total cpu time spent up to now is      385.5 secs

     total energy              =     307.99567366 Ry
     Harris-Foulkes estimate   =     307.99515417 Ry
     estimated scf accuracy    <       0.00240390 Ry

     iteration # 10     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  5.51E-06,  avg # of iterations =  6.3

     total cpu time spent up to now is      416.2 secs

     total energy              =     307.99540908 Ry
     Harris-Foulkes estimate   =     307.99536537 Ry
     estimated scf accuracy    <       0.00021549 Ry

     iteration # 11     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  7.70E-07,  avg # of iterations =  5.3

     total cpu time spent up to now is      446.2 secs

     total energy              =     307.99538489 Ry
     Harris-Foulkes estimate   =     307.99537273 Ry
     estimated scf accuracy    <       0.00005225 Ry

     iteration # 12     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.87E-07,  avg # of iterations =  6.4

     total cpu time spent up to now is      480.2 secs

     total energy              =     307.99537052 Ry
     Harris-Foulkes estimate   =     307.99536595 Ry
     estimated scf accuracy    <       0.00003550 Ry

     iteration # 13     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.27E-07,  avg # of iterations =  1.2

     total cpu time spent up to now is      504.0 secs

     total energy              =     307.99537535 Ry
     Harris-Foulkes estimate   =     307.99536956 Ry
     estimated scf accuracy    <       0.00001829 Ry

     iteration # 14     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  6.53E-08,  avg # of iterations =  6.5

     total cpu time spent up to now is      540.4 secs

     total energy              =     307.99536905 Ry
     Harris-Foulkes estimate   =     307.99536224 Ry
     estimated scf accuracy    <       0.00008863 Ry

     iteration # 15     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  6.53E-08,  avg # of iterations =  2.2

     total cpu time spent up to now is      565.0 secs

     total energy              =     307.99537093 Ry
     Harris-Foulkes estimate   =     307.99536822 Ry
     estimated scf accuracy    <       0.00004959 Ry

     iteration # 16     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  6.53E-08,  avg # of iterations =  1.7

     total cpu time spent up to now is      589.9 secs

     total energy              =     307.99537315 Ry
     Harris-Foulkes estimate   =     307.99537023 Ry
     estimated scf accuracy    <       0.00003088 Ry

     iteration # 17     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  6.53E-08,  avg # of iterations =  6.1

     total cpu time spent up to now is      620.9 secs

     total energy              =     307.99536838 Ry
     Harris-Foulkes estimate   =     307.99536834 Ry
     estimated scf accuracy    <       0.00000356 Ry

     iteration # 18     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.27E-08,  avg # of iterations =  2.5

     total cpu time spent up to now is      646.4 secs

     total energy              =     307.99536851 Ry
     Harris-Foulkes estimate   =     307.99536814 Ry
     estimated scf accuracy    <       0.00000471 Ry

     iteration # 19     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.27E-08,  avg # of iterations =  1.1

     total cpu time spent up to now is      671.3 secs

     total energy              =     307.99536876 Ry
     Harris-Foulkes estimate   =     307.99536846 Ry
     estimated scf accuracy    <       0.00000321 Ry

     iteration # 20     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.15E-08,  avg # of iterations =  2.9

     total cpu time spent up to now is      697.5 secs

     total energy              =     307.99536860 Ry
     Harris-Foulkes estimate   =     307.99536860 Ry
     estimated scf accuracy    <       0.00000054 Ry

     iteration # 21     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  1.91E-09,  avg # of iterations =  5.7

     total cpu time spent up to now is      728.7 secs

     total energy              =     307.99536848 Ry
     Harris-Foulkes estimate   =     307.99536848 Ry
     estimated scf accuracy    <       0.00000003 Ry

     iteration # 22     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  9.53E-11,  avg # of iterations =  6.3

     total cpu time spent up to now is      762.6 secs

     total energy              =     307.99536847 Ry
     Harris-Foulkes estimate   =     307.99536847 Ry
     estimated scf accuracy    <       0.00000002 Ry

     iteration # 23     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  5.82E-11,  avg # of iterations =  2.6

     total cpu time spent up to now is      788.2 secs

     total energy              =     307.99536846 Ry
     Harris-Foulkes estimate   =     307.99536847 Ry
     estimated scf accuracy    <       0.00000001 Ry

     iteration # 24     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.91E-11,  avg # of iterations =  6.4

     total cpu time spent up to now is      827.1 secs

     total energy              =     307.99536845 Ry
     Harris-Foulkes estimate   =     307.99536845 Ry
     estimated scf accuracy    <       0.00000020 Ry

     iteration # 25     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.91E-11,  avg # of iterations =  1.0

     total cpu time spent up to now is      851.2 secs

     total energy              =     307.99536846 Ry
     Harris-Foulkes estimate   =     307.99536845 Ry
     estimated scf accuracy    <       0.00000021 Ry

     iteration # 26     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.91E-11,  avg # of iterations =  6.4

     total cpu time spent up to now is      886.0 secs

     total energy              =     307.99536846 Ry
     Harris-Foulkes estimate   =     307.99536845 Ry
     estimated scf accuracy    <       0.00000018 Ry

     iteration # 27     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.91E-11,  avg # of iterations =  1.0

     total cpu time spent up to now is      910.6 secs

     total energy              =     307.99536846 Ry
     Harris-Foulkes estimate   =     307.99536846 Ry
     estimated scf accuracy    <       0.00000016 Ry

     iteration # 28     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.91E-11,  avg # of iterations =  1.0

     total cpu time spent up to now is      936.1 secs

     total energy              =     307.99536847 Ry
     Harris-Foulkes estimate   =     307.99536846 Ry
     estimated scf accuracy    <       0.00000015 Ry

     iteration # 29     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.91E-11,  avg # of iterations =  6.5

     total cpu time spent up to now is      975.9 secs

     total energy              =     307.99536847 Ry
     Harris-Foulkes estimate   =     307.99536846 Ry
     estimated scf accuracy    <       0.00000002 Ry

     iteration # 30     ecut=    20.00 Ry     beta=0.70
     Davidson diagonalization with overlap
     ethr =  4.91E-11,  avg # of iterations =  5.0

     total cpu time spent up to now is     1005.8 secs

     End of self-consistent calculation

          k = 0.0000 0.0000 0.0000 (  1709 PWs)   bands (ev):

   -51.5827 -25.8230 -24.9786 -24.7451  -7.3209  -2.4046  -2.0725  -0.7164
    -0.4321   2.2907   3.0790   3.6528   4.2659   4.4055

          k = 0.0000 0.4201 0.0489 (  1728 PWs)   bands (ev):

   -51.5875 -25.8654 -24.9981 -24.7862  -7.1371  -2.3388  -2.1848  -0.6728
    -0.4611   2.2550   3.3082   3.7701   4.2621   4.4451

          k = 0.0000 0.8402 0.0978 (  1737 PWs)   bands (ev):

   -51.5842 -25.9430 -25.0261 -24.8229  -6.7292  -2.4595  -1.9952  -0.5543
    -0.5109   2.2858   3.5318   3.9686   4.3385   4.4107

          k = 0.0000 1.2602 0.1467 (  1739 PWs)   bands (ev):

   -51.5793 -26.0107 -25.0536 -24.8569  -6.4202  -2.6050  -1.5863  -0.5938
    -0.4676   2.3259   3.5227   4.0177   4.2123   4.3526

          k = 0.3638 0.2100 0.0978 (  1727 PWs)   bands (ev):

   -51.5849 -25.8776 -25.0006 -24.7795  -7.1029  -2.3353  -2.0248  -0.6946
    -0.4733   2.0960   3.3137   3.7930   4.3369   4.4321

          k = 0.3638 0.6301 0.1467 (  1724 PWs)   bands (ev):

   -51.5758 -25.9488 -25.0310 -24.7830  -6.7083  -2.2618  -1.9605  -0.5997
    -0.4844   2.0695   3.5094   3.8917   4.3356   4.3894

          k = 0.3638 1.0502 0.1956 (  1734 PWs)   bands (ev):

   -51.5763 -26.0197 -25.0445 -24.8331  -6.3961  -2.4247  -1.5739  -0.5971
    -0.4894   2.2122   3.5677   3.8524   4.1411   4.3317

          k = 0.3638-1.4703-0.0978 (  1728 PWs)   bands (ev):

   -51.5737 -26.0145 -25.0551 -24.8640  -6.3691  -2.4776  -1.6100  -0.6002
    -0.4374   2.3721   3.5607   3.9355   4.1776   4.3566

          k = 0.3638-1.0502-0.0489 (  1735 PWs)   bands (ev):

   -51.5855 -25.9494 -25.0264 -24.8855  -6.6509  -2.3996  -2.0520  -0.5650
    -0.4913   2.4462   3.5248   3.9897   4.3653   4.5662

          k = 0.3638-0.6301-0.0000 (  1724 PWs)   bands (ev):

   -51.5881 -25.8684 -24.9972 -24.8457  -7.0491  -2.3463  -2.1968  -0.5898
    -0.5209   2.4254   3.3655   3.9918   4.3841   4.6339

          k = 0.7276 0.4201 0.1956 (  1732 PWs)   bands (ev):

   -51.5803 -25.9849 -25.0393 -24.8254  -6.6192  -2.0706  -1.8843  -0.6379
    -0.5323   2.0582   3.4393   3.8413   4.3253   4.5766

          k = 0.7276 0.8402 0.2445 (  1736 PWs)   bands (ev):

   -51.5729 -26.0520 -25.0620 -24.8321  -6.3260  -2.0774  -1.5836  -0.6397
    -0.5120   2.1508   3.4738   3.7960   4.0135   4.4138

          k = 0.7276-1.6803-0.0489 (  1725 PWs)   bands (ev):

   -51.5708 -26.0392 -25.0536 -24.8693  -6.2922  -2.1299  -1.6351  -0.6288
    -0.4566   2.3717   3.6697   3.7624   4.0687   4.3649

          k = 0.7276-1.2602-0.0000 (  1726 PWs)   bands (ev):

   -51.5768 -25.9694 -25.0285 -24.9143  -6.5484  -2.1205  -2.0707  -0.5852
    -0.4552   2.4934   3.6147   3.9179   4.2532   4.5306

          k = 1.0914 0.6301 0.2934 (  1740 PWs)   bands (ev):

   -51.5788 -26.0793 -25.0700 -24.8587  -6.2654  -1.8402  -1.6079  -0.6958
    -0.5318   2.3081   3.3800   3.7746   3.9756   4.4733

          k = 1.0914-1.8904-0.0000 (  1736 PWs)   bands (ev):

   -51.5732 -26.0738 -25.0688 -24.8684  -6.2559  -1.8454  -1.6316  -0.6765
    -0.5081   2.4015   3.4945   3.8128   3.9787   4.4176

          k =-0.3638-0.2100 0.0489 (  1728 PWs)   bands (ev):

   -51.5855 -25.8787 -25.0008 -24.7856  -7.1021  -2.3328  -2.0293  -0.6978
    -0.4759   2.0972   3.3128   3.7914   4.3369   4.4313

          k = 0.3638-0.2100 0.0489 (  1728 PWs)   bands (ev):

   -51.5882 -25.8440 -24.9855 -24.7976  -7.2657  -2.4252  -2.0188  -0.6932
    -0.4936   2.2918   3.1867   3.8483   4.3003   4.5813

          k =-0.7276-0.4201 0.0978 (  1737 PWs)   bands (ev):

   -51.5821 -25.9881 -25.0471 -24.8256  -6.6179  -2.0712  -1.8885  -0.6466
    -0.5394   2.0575   3.4348   3.8404   4.3204   4.5761

          k = 0.7276-0.4201 0.0978 (  1737 PWs)   bands (ev):

   -51.5871 -25.8708 -25.0010 -24.8718  -7.1355  -2.4899  -1.8162  -0.6112
    -0.5712   2.4018   3.3677   4.1556   4.3032   4.6113

          k =-1.0914-0.6301 0.1467 (  1739 PWs)   bands (ev):

   -51.5784 -26.0761 -25.0554 -24.8517  -6.2703  -1.8354  -1.6080  -0.6874
    -0.5293   2.3098   3.3827   3.7767   3.9733   4.4770

          k = 1.0914-0.6301 0.1467 (  1739 PWs)   bands (ev):

   -51.5851 -25.8891 -25.0251 -24.9086  -7.0425  -2.5395  -1.6236  -0.6415
    -0.5134   2.5005   3.6739   4.0963   4.2866   4.5587

          k = 0.3638-0.2100-0.0978 (  1727 PWs)   bands (ev):

   -51.5875 -25.8447 -24.9884 -24.8026  -7.2621  -2.4237  -2.0178  -0.6944
    -0.4878   2.2929   3.1856   3.8479   4.2997   4.5830

          k = 0.0000-0.4201 0.0978 (  1727 PWs)   bands (ev):

   -51.5872 -25.8642 -25.0029 -24.7789  -7.1376  -2.3397  -2.1846  -0.6656
    -0.4694   2.2541   3.3080   3.7719   4.2615   4.4452

          k = 0.3638-0.6301-0.1467 (  1724 PWs)   bands (ev):

   -51.5857 -25.8680 -24.9944 -24.8393  -7.0525  -2.3424  -2.1978  -0.5853
    -0.5164   2.4232   3.3665   3.9905   4.3848   4.6322

          k =-0.7276 0.0000 0.1467 (  1724 PWs)   bands (ev):

   -51.5803 -25.9012 -25.0199 -24.8278  -6.9808  -2.3664  -1.7809  -0.6508
    -0.5381   2.1910   3.3642   3.9564   4.3794   4.6485

          k = 0.3638-0.6301 0.1467 (  1724 PWs)   bands (ev):

   -51.5874 -25.8674 -24.9953 -24.8415  -7.0524  -2.3471  -2.1945  -0.5860
    -0.5241   2.4228   3.3651   3.9926   4.3841   4.6321

          k =-0.7276-0.0000-0.1467 (  1724 PWs)   bands (ev):

   -51.5791 -25.9019 -25.0114 -24.8302  -6.9794  -2.3663  -1.7792  -0.6432
    -0.5415   2.1911   3.3668   3.9575   4.3783   4.6492

          k = 0.3638 0.6301-0.1467 (  1724 PWs)   bands (ev):

   -51.5797 -25.9487 -25.0350 -24.7811  -6.7072  -2.2653  -1.9645  -0.6078
    -0.4870   2.0709   3.5107   3.8919   4.3388   4.3908

          k = 0.3638-1.0502-0.1956 (  1734 PWs)   bands (ev):

   -51.5822 -25.9497 -25.0208 -24.8907  -6.6512  -2.3973  -2.0462  -0.5506
    -0.4879   2.4444   3.5258   3.9908   4.3634   4.5660

          k =-1.0914-0.2100 0.1956 (  1734 PWs)   bands (ev):

   -51.5787 -26.0077 -25.0468 -24.8669  -6.5277  -2.0806  -1.7125  -0.6435
    -0.5515   2.3168   3.5135   3.8701   4.2592   4.4626

          k = 0.7276-0.8402 0.1956 (  1734 PWs)   bands (ev):

   -51.5828 -25.8972 -25.0031 -24.9256  -6.9331  -2.4108  -1.9567  -0.5846
    -0.5058   2.5006   3.5020   4.0688   4.4390   4.5356

          k =-1.0914 0.2100-0.1956 (  1734 PWs)   bands (ev):

   -51.5829 -25.9247 -25.0255 -24.8869  -6.8834  -2.4274  -1.6197  -0.6373
    -0.5447   2.4241   3.5990   4.0476   4.2443   4.5633

          k = 0.7276 0.8402-0.1956 (  1734 PWs)   bands (ev):

   -51.5742 -26.0494 -25.0564 -24.8402  -6.3262  -2.0774  -1.5843  -0.6404
    -0.5146   2.1519   3.4751   3.8001   4.0169   4.4176

          k = 0.3638 1.4703 0.0978 (  1728 PWs)   bands (ev):

   -51.5756 -26.0140 -25.0519 -24.8687  -6.3661  -2.4813  -1.6111  -0.6092
    -0.4402   2.3735   3.5614   3.9349   4.1793   4.3551

          k = 1.0914 1.0502-0.0978 (  1728 PWs)   bands (ev):

   -51.5708 -26.0678 -25.0552 -24.8724  -6.2515  -1.8408  -1.6239  -0.6681
    -0.5003   2.4106   3.4978   3.8164   3.9777   4.4212

          k =-1.4552 0.4201-0.0978 (  1728 PWs)   bands (ev):

   -51.5789 -25.9152 -25.0235 -24.9270  -6.8609  -2.4438  -1.6908  -0.6245
    -0.4737   2.5151   3.7077   4.0176   4.2966   4.6029

          k = 1.0914-1.0502 0.0978 (  1728 PWs)   bands (ev):

   -51.5777 -25.9155 -25.0282 -24.9174  -6.8608  -2.4441  -1.6880  -0.6197
    -0.4725   2.5152   3.7083   4.0183   4.2955   4.6034

          k =-1.4552-0.4201 0.0978 (  1728 PWs)   bands (ev):

   -51.5737 -26.0669 -25.0503 -24.8624  -6.2543  -1.8425  -1.6315  -0.6764
    -0.4964   2.4103   3.4997   3.8184   3.9791   4.4221

          k = 0.3638 1.0502 0.0489 (  1735 PWs)   bands (ev):

   -51.5753 -26.0199 -25.0553 -24.8280  -6.3966  -2.4222  -1.5735  -0.5956
    -0.4850   2.2100   3.5658   3.8523   4.1406   4.3318

          k = 0.7276 0.8402-0.0489 (  1735 PWs)   bands (ev):

   -51.5736 -26.0500 -25.0596 -24.8371  -6.3265  -2.0741  -1.5866  -0.6364
    -0.5116   2.1530   3.4738   3.7984   4.0140   4.4159

          k =-1.0914 0.2100-0.0489 (  1735 PWs)   bands (ev):

   -51.5812 -25.9248 -25.0317 -24.8839  -6.8846  -2.4256  -1.6204  -0.6280
    -0.5499   2.4214   3.5980   4.0469   4.2452   4.5608

          k = 0.7276-0.8402 0.0489 (  1735 PWs)   bands (ev):

   -51.5856 -25.8974 -25.0035 -24.9215  -6.9312  -2.4176  -1.9613  -0.5934
    -0.5081   2.5028   3.5019   4.0685   4.4399   4.5360

          k =-1.0914-0.2100 0.0489 (  1735 PWs)   bands (ev):

   -51.5784 -26.0072 -25.0504 -24.8616  -6.5303  -2.0802  -1.7150  -0.6409
    -0.5550   2.3168   3.5131   3.8698   4.2572   4.4604

          k = 0.3638 0.6301 0.0000 (  1724 PWs)   bands (ev):

   -51.5779 -25.9484 -25.0253 -24.7802  -6.7078  -2.2626  -1.9639  -0.6042
    -0.4822   2.0696   3.5119   3.8925   4.3384   4.3882

          k =-0.7276 0.0000-0.0000 (  1724 PWs)   bands (ev):

   -51.5802 -25.8998 -25.0076 -24.8267  -6.9836  -2.3639  -1.7842  -0.6478
    -0.5393   2.1897   3.3648   3.9579   4.3796   4.6501

          k = 0.7276-0.4201-0.1956 (  1732 PWs)   bands (ev):

   -51.5853 -25.8677 -25.0009 -24.8748  -7.1343  -2.4825  -1.8168  -0.6035
    -0.5694   2.4025   3.3663   4.1558   4.3032   4.6127

          k = 0.0000-0.8402 0.1956 (  1732 PWs)   bands (ev):

   -51.5812 -25.9408 -25.0292 -24.8261  -6.7269  -2.4553  -1.9912  -0.5400
    -0.5066   2.2863   3.5318   3.9696   4.3408   4.4117

          k = 0.7276-0.8402-0.2445 (  1736 PWs)   bands (ev):

   -51.5843 -25.8984 -25.0108 -24.9265  -6.9307  -2.4132  -1.9602  -0.5997
    -0.5028   2.5013   3.4981   4.0681   4.4384   4.5343

          k =-1.0914 0.2100 0.2445 (  1736 PWs)   bands (ev):

   -51.5824 -25.9260 -25.0297 -24.8896  -6.8827  -2.4266  -1.6228  -0.6302
    -0.5572   2.4217   3.5975   4.0459   4.2444   4.5587

          k = 0.3638-1.0502 0.2445 (  1736 PWs)   bands (ev):

   -51.5816 -25.9523 -25.0319 -24.8831  -6.6490  -2.3972  -2.0475  -0.5628
    -0.4851   2.4448   3.5222   3.9879   4.3581   4.5661

          k =-1.0914-0.2100-0.2445 (  1736 PWs)   bands (ev):

   -51.5798 -26.0077 -25.0502 -24.8598  -6.5332  -2.0873  -1.7109  -0.6395
    -0.5550   2.3161   3.5147   3.8695   4.2576   4.4609

          k = 0.3638 1.0502-0.2445 (  1736 PWs)   bands (ev):

   -51.5773 -26.0201 -25.0527 -24.8307  -6.3988  -2.4243  -1.5760  -0.5948
    -0.4937   2.2095   3.5657   3.8524   4.1411   4.3325

          k = 0.7276 1.6803 0.0489 (  1725 PWs)   bands (ev):

   -51.5764 -25.9702 -25.0326 -24.9172  -6.5459  -2.1208  -2.0665  -0.5995
    -0.4406   2.4939   3.6128   3.9192   4.2544   4.5289

          k = 1.0914 1.4703-0.0489 (  1725 PWs)   bands (ev):

   -51.5716 -25.9957 -25.0380 -24.9079  -6.5000  -2.1039  -1.7746  -0.6227
    -0.4722   2.4767   3.6875   3.9078   4.2017   4.5174

          k =-1.8190 0.2100-0.0489 (  1725 PWs)   bands (ev):

   -51.5746 -25.9701 -25.0361 -24.9193  -6.5473  -2.1187  -2.0650  -0.5958
    -0.4375   2.4927   3.6169   3.9181   4.2526   4.5290

          k = 1.0914-1.4703 0.0489 (  1725 PWs)   bands (ev):

   -51.5712 -25.9955 -25.0467 -24.9025  -6.5002  -2.1053  -1.7740  -0.6269
    -0.4683   2.4759   3.6875   3.9073   4.2013   4.5173

          k =-1.8190-0.2100 0.0489 (  1725 PWs)   bands (ev):

   -51.5705 -26.0384 -25.0479 -24.8703  -6.2953  -2.1293  -1.6348  -0.6262
    -0.4584   2.3724   3.6701   3.7616   4.0716   4.3649

          k = 0.7276 1.2602 0.0000 (  1726 PWs)   bands (ev):

   -51.5708 -26.0392 -25.0521 -24.8692  -6.2923  -2.1297  -1.6363  -0.6271
    -0.4643   2.3723   3.6683   3.7603   4.0679   4.3641

          k =-1.4552-0.0000-0.0000 (  1726 PWs)   bands (ev):

   -51.5746 -25.9952 -25.0392 -24.8994  -6.5004  -2.1123  -1.7775  -0.6250
    -0.4845   2.4765   3.6854   3.9068   4.2024   4.5168

          k = 1.0914-0.6301-0.2934 (  1740 PWs)   bands (ev):

   -51.5843 -25.8896 -25.0163 -24.9175  -7.0458  -2.5422  -1.6173  -0.6424
    -0.5085   2.4976   3.6771   4.0963   4.2857   4.5581

          k = 0.0000-1.2602 0.2934 (  1740 PWs)   bands (ev):

   -51.5786 -26.0110 -25.0444 -24.8570  -6.4233  -2.6111  -1.5807  -0.5886
    -0.4670   2.3272   3.5250   4.0170   4.2097   4.3534

          k = 1.0914 1.8904 0.0000 (  1736 PWs)   bands (ev):

   -51.5817 -25.9210 -25.0260 -24.9333  -6.8629  -2.4484  -1.6948  -0.6392
    -0.4806   2.5119   3.7061   4.0169   4.2916   4.6000

          k =-2.1828 0.0000-0.0000 (  1736 PWs)   bands (ev):

   -51.5790 -26.0199 -25.0467 -24.8688  -6.3712  -2.4860  -1.6187  -0.6090
    -0.4531   2.3693   3.5608   3.9319   4.1750   4.3565

!    total energy              =     307.99536847 Ry
     Harris-Foulkes estimate   =     307.99536847 Ry
     estimated scf accuracy    <          3.7E-09 Ry

     The total energy is the sum of the following terms:

     one-electron contribution =    -373.71256696 Ry
     hartree contribution      =     195.30418819 Ry
     xc contribution           =     -26.64451511 Ry
     ewald contribution        =     513.04826235 Ry

     convergence has been achieved in  30 iterations

     Forces acting on atoms (Ry/au):

     atom    1 type  1   force =    65.43446471   65.42533969   65.42845937
     atom    2 type  1   force =   -39.98837920  -39.97896189  -39.94906074
     atom    3 type  2   force =   148.86971851  148.86160168  148.92941675
     atom    4 type  2   force =   -69.52414233  -69.51568720  -69.58409401
     atom    5 type  3   force =  -104.79166169 -104.79229228 -104.82472138

     Total force =   362.763292     Total SCF correction =     0.000163


     entering subroutine stress ...

          total   stress  (Ry/bohr**3)                   (kbar)
P=24248.94
   0.16474447   0.16704983   0.16696437      24234.74  24573.87  24561.30
   0.16704983   0.16464995   0.16695682      24573.87  24220.84  24560.19
   0.16696437   0.16695682   0.16512844      24561.30  24560.19  24291.23


     Writing output data file Bi2Te2SRH_exc1.save

     init_run     :     31.46s CPU     31.66s WALL (       1 calls)
     electrons    :    966.22s CPU    973.94s WALL (       1 calls)
     forces       :      1.27s CPU      1.28s WALL (       1 calls)
     stress       :      2.90s CPU      3.01s WALL (       1 calls)

     Called by init_run:
     wfcinit      :     30.47s CPU     30.64s WALL (       1 calls)
     potinit      :      0.36s CPU      0.37s WALL (       1 calls)

     Called by electrons:
     c_bands      :    825.93s CPU    832.30s WALL (      30 calls)
     sum_band     :    133.86s CPU    134.56s WALL (      30 calls)
     v_of_rho     :      5.86s CPU      6.15s WALL (      31 calls)
     mix_rho      :      0.34s CPU      0.34s WALL (      30 calls)

     Called by c_bands:
     init_us_2    :      5.90s CPU      6.48s WALL (    4032 calls)
     cegterg      :    811.64s CPU    816.39s WALL (    1920 calls)

     Called by *egterg:
     h_psi        :    799.79s CPU    803.81s WALL (   10590 calls)
     g_psi        :      1.70s CPU      1.74s WALL (    8606 calls)
     cdiaghg      :      6.48s CPU      6.70s WALL (   10526 calls)

     Called by h_psi:
     add_vuspsi   :     17.46s CPU     17.33s WALL (   10590 calls)

     General routines
     calbec       :     20.34s CPU     20.37s WALL (   10718 calls)
     fft          :      2.31s CPU      2.39s WALL (     348 calls)
     fftw         :    807.28s CPU    812.56s WALL (  184596 calls)
     davcio       :      0.52s CPU      1.30s WALL (    5952 calls)


     PWSCF        : 16m42.21s CPU    16m50.46s WALL


   This run was terminated on:  12: 1:18  12Jan2014

=------------------------------------------------------------------------------=
   JOB DONE.
Thanks ALLASSAN SHUAIBU
PhD Theoretical Physics
UPM Malaysia
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