[Pw_forum] Reg: How to know the mode name and due to which atom it is happening?

Paolo Giannozzi paolo.giannozzi at uniud.it
Tue Apr 1 19:00:35 CEST 2014


Look at the displacement patterns: they correspond to
rigid translations of all atoms. T_1u, G_15, G_4-, are 
symmetry labels (G stands for Gamma) for threefold 
degenerate odd-parity (u, -) irreducible representation 
of cubic groups.

P.

On Tue, 2014-04-01 at 19:53 +0530, Peram sreenivasa reddy wrote:
>  Dear xirainbow,
> 
> 
> Thank you very much  for your replay.
> 
> 
> 
> In my case.dyn1 file (given bellow), the  omega(1), omega(2) and
> omega(3)  have same values as -16.572332 [cm-1]. In my plot i got
> imaginary for only one mode along gamma to X direction. In case.ph.out
> file the same only it is writing as bellow
> 
> omega(  1 -  3) =        -16.6  [cm-1]   --> T_1u G_15  G_4- I
>   omega(  4 -  6) =        122.3  [cm-1]   --> T_1u G_15  G_4- I
>   omega(  7 -  9) =        145.0  [cm-1]   --> T_2g G_25' G_5+ R
>   omega( 10 - 12) =        258.5  [cm-1]   --> T_1u G_15  G_4- I
> 
> 
> My question is
> 
> 
> I want to know among T_1u, G_15 and  G_4- , which is belongs to that
> imaginary one?. and This is due to which atom ?.
> 
> 
> Here i am giving the case.dyn1 file
> 
> Dynamical matrix file
> 
>   3    4  2 12.9257258  0.0000000  0.0000000  0.0000000  0.0000000
> 0.0000000
> 
>            1  'X  '    83145.5895442744
> 
>            2  'Y  '    43628.1015381455
> 
>            3  'Z  '    24592.5885412130
> 
>     1    1      0.2500000      0.2500000      0.2500000
>     2    1      0.7500000      0.7500000      0.7500000
>     3    2      0.0000000      0.0000000      0.5000000
>     4    3      0.0000000      0.0000000      0.0000000
> 
> 
> 
>   Diagonalizing the dynamical matrix
> 
>      q = (    0.000000000   0.000000000   0.000000000 )
> 
>  **************************************************************************
>      omega( 1) =      -0.496826 [THz] =     -16.572332 [cm-1]
>  ( -0.474725  0.000000 -0.149266  0.000000  0.011949  0.000000 )
>  ( -0.474725  0.000000 -0.149266  0.000000  0.011949  0.000000 )
>  ( -0.478986  0.000000 -0.150606  0.000000  0.012057  0.000000 )
>  ( -0.478907  0.000000 -0.150581  0.000000  0.012055  0.000000 )
>      omega( 2) =      -0.496826 [THz] =     -16.572332 [cm-1]
>  (  0.115254  0.000000 -0.389580  0.000000 -0.287630  0.000000 )
>  (  0.115254  0.000000 -0.389580  0.000000 -0.287630  0.000000 )
>  (  0.116289  0.000000 -0.393077  0.000000 -0.290211  0.000000 )
>  (  0.116269  0.000000 -0.393012  0.000000 -0.290163  0.000000 )
>      omega( 3) =      -0.496826 [THz] =     -16.572332 [cm-1]
>  ( -0.095601  0.000000  0.271540  0.000000 -0.406095  0.000000 )
>  ( -0.095601  0.000000  0.271540  0.000000 -0.406095  0.000000 )
>  ( -0.096459  0.000000  0.273977  0.000000 -0.409740  0.000000 )
>  ( -0.096443  0.000000  0.273932  0.000000 -0.409672  0.000000 )
>      omega( 4) =       3.667733 [THz] =     122.342418 [cm-1]
>  ( -0.030936  0.000000  0.147451  0.000000  0.112884  0.000000 )
>  ( -0.030936  0.000000  0.147451  0.000000  0.112884  0.000000 )
>  (  0.148268  0.000000 -0.706706  0.000000 -0.541030  0.000000 )
>  ( -0.055722  0.000000  0.265593  0.000000  0.203329  0.000000 )
>      omega( 5) =       3.667733 [THz] =     122.342418 [cm-1]
>  ( -0.178977  0.000000 -0.054189  0.000000  0.021734  0.000000 )
>  ( -0.178977  0.000000 -0.054189  0.000000  0.021734  0.000000 )
>  (  0.857803  0.000000  0.259716  0.000000 -0.104167  0.000000 )
>  ( -0.322379  0.000000 -0.097606  0.000000  0.039148  0.000000 )
>      omega( 6) =       3.667733 [THz] =     122.342418 [cm-1]
>  (  0.049515  0.000000 -0.103746  0.000000  0.149085  0.000000 )
>  (  0.049515  0.000000 -0.103746  0.000000  0.149085  0.000000 )
>  ( -0.237317  0.000000  0.497237  0.000000 -0.714539  0.000000 )
>  (  0.089188  0.000000 -0.186871  0.000000  0.268537  0.000000 )
>      omega( 7) =       4.346354 [THz] =     144.978757 [cm-1]
>  ( -0.661366  0.000000 -0.216095  0.000000  0.126085  0.000000 )
>  (  0.661366  0.000000  0.216095  0.000000 -0.126085  0.000000 )
>  (  0.000000  0.000000  0.000000  0.000000  0.000000  0.000000 )
>  (  0.000000  0.000000  0.000000  0.000000  0.000000  0.000000 )
>      omega( 8) =       4.346354 [THz] =     144.978757 [cm-1]
>  (  0.016908  0.000000 -0.394145  0.000000 -0.586825  0.000000 )
>  ( -0.016908  0.000000  0.394145  0.000000  0.586825  0.000000 )
>  (  0.000000  0.000000  0.000000  0.000000  0.000000  0.000000 )
>  (  0.000000  0.000000  0.000000  0.000000  0.000000  0.000000 )
>      omega( 9) =       4.346354 [THz] =     144.978757 [cm-1]
>  ( -0.249617  0.000000  0.545851  0.000000 -0.373816  0.000000 )
>  (  0.249617  0.000000 -0.545851  0.000000  0.373816  0.000000 )
>  (  0.000000  0.000000  0.000000  0.000000  0.000000  0.000000 )
>  (  0.000000  0.000000  0.000000  0.000000  0.000000  0.000000 )
>      omega(10) =       7.750968 [THz] =     258.544478 [cm-1]
>  (  0.152212  0.000000  0.015908  0.000000 -0.060146  0.000000 )
>  (  0.152212  0.000000  0.015908  0.000000 -0.060146  0.000000 )
>  ( -0.069108  0.000000 -0.007223  0.000000  0.027308  0.000000 )
>  ( -0.897629  0.000000 -0.093813  0.000000  0.354696  0.000000 )
>      omega(11) =       7.750968 [THz] =     258.544478 [cm-1]
>  ( -0.060461  0.000000  0.075301  0.000000 -0.133092  0.000000 )
>  ( -0.060461  0.000000  0.075301  0.000000 -0.133092  0.000000 )
>  (  0.027451  0.000000 -0.034188  0.000000  0.060427  0.000000 )
>  (  0.356551  0.000000 -0.444063  0.000000  0.784874  0.000000 )
>      omega(12) =       7.750968 [THz] =     258.544478 [cm-1]
>  ( -0.014667  0.000000 -0.145314  0.000000 -0.075552  0.000000 )
>  ( -0.014667  0.000000 -0.145314  0.000000 -0.075552  0.000000 )
>  (  0.006659  0.000000  0.065976  0.000000  0.034302  0.000000 )
>  (  0.086496  0.000000  0.856945  0.000000  0.445546  0.000000 )
>  **************************************************************************
> 
> Thank you.
> 
> 
> 
> 
> 
> On Tue, Apr 1, 2014 at 7:28 PM, xirainbow <nkxirainbow at gmail.com>
> wrote:
>         Dear
>         In my calculation, the end of the *.dyn1 file looks like the
>         following content:
>         
>         "     Diagonalizing the dynamical matrix
>         
>              q = (    0.000000000   0.000000000   0.000000000 )
>         
>          **************************************************************************
>              omega( 1) =       XX [THz] =      XX [cm-1]
>          (  0.142825  0.000000  0.142825  0.000000  0.323621  0.000000
>         )
>          ( -0.142825  0.000000 -0.142825  0.000000  0.323621  0.000000
>         )
>          ( -0.142825  0.000000  0.142825  0.000000  0.323621  0.000000
>         )
>          (  0.142825  0.000000 -0.142825  0.000000  0.323621  0.000000
>         )
>              omega( 2) =       XX [THz] =      XX [cm-1]
>          ( -0.226720  0.000000  0.264038  0.000000 -0.002735  0.000000
>         )
>          ( -0.226720  0.000000  0.264038  0.000000  0.002735  0.000000
>         )
>          ( -0.269604  0.000000  0.301664  0.000000 -0.041874  0.000000
>         )
>          ( -0.269604  0.000000  0.301664  0.000000  0.041874  0.000000
>         )
>         
>         ..................................."
>         
>         On Tue, Apr 1, 2014 at 7:49 PM, Peram sreenivasa reddy
>         <peramsreenivas at gmail.com> wrote:
>         > Dear xirainbow,
>         >
>         > Thank you very much for your replay.
>         >
>         > In that case.dyn1 file also it is giving same only as in the
>         case.ph.out
>         > file.
>         >
>         > Please give me more clarification.
>         >
>         > Thanking you.
>         >
>         >
>         > On Tue, Apr 1, 2014 at 3:15 PM, xirainbow
>         <nkxirainbow at gmail.com> wrote:
>         >>
>         >> You can find the answer at the end of  *.dyn* files.
>         >>
>         >> On Mon, Mar 31, 2014 at 11:10 PM, Peram sreenivasa reddy
>         >> <peramsreenivas at gmail.com> wrote:
>         >> > Dear Pwscf,
>         >> >
>         >> > In my phonon calculations i got one imaginary mode in
>         gamma to X
>         >> > direction.
>         >> > I want to know which mode it is? and due to which atom it
>         is happening?
>         >> >
>         >> > I checked the case.ph.out file. In this file it is given
>         like below.
>         >> >
>         >> > Mode symmetry, O_h (m-3m)  point group:
>         >> >   omega(  1 -  3) =        -16.6  [cm-1]   --> T_1u G_15
>          G_4- I
>         >> >   omega(  4 -  6) =        122.3  [cm-1]   --> T_1u G_15
>          G_4- I
>         >> >   omega(  7 -  9) =        145.0  [cm-1]   --> T_2g G_25'
>         G_5+ R
>         >> >   omega( 10 - 12) =        258.5  [cm-1]   --> T_1u G_15
>          G_4- I
>         >> >
>         >> > Here i am attaching the case.agr file
>         >> >
>         >> > Here all acoustic modes are given with same frequency.
>         How can know that
>         >> > particular mode name.
>         >> >
>         >> >
>         >> >  My system is X2YZ type. How can i know this imaginary
>         mode is due to
>         >> > which
>         >> > atom. I plotted partial phonon density of states also.
>         But all atoms are
>         >> > giving same contribution in this acoustic mode region.
>         >> >
>         >> >  Thank you in advance.
>         >> >
>         >> >
>         >> >
>         >> > _______________________________________________
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>         >>
>         >>
>         >>
>         >> --
>         >> ____________________________________
>         >> Hui Wang
>         >> School of physics, Henan University of Science and
>         Technology, Henan,
>         >> China
>         >> _______________________________________________
>         >> Pw_forum mailing list
>         >> Pw_forum at pwscf.org
>         >> http://pwscf.org/mailman/listinfo/pw_forum
>         >
>         >
>         >
>         >
>         >
>         >
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>         
>         
>         
>         --
>         ____________________________________
>         Hui Wang
>         School of physics, Henan University of Science and Technology,
>         Henan, China
>         _______________________________________________
>         Pw_forum mailing list
>         Pw_forum at pwscf.org
>         http://pwscf.org/mailman/listinfo/pw_forum
>         
> 
> 
> 
> 
> 
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-- 
Paolo Giannozzi, Dept. Chemistry&Physics&Environment, 
Univ. Udine, via delle Scienze 208, 33100 Udine, Italy
Phone +39-0432-558216, fax +39-0432-558222 




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