[Pw_forum] vc-md temperature increases

Lily Anh lily_physics at yahoo.com.sg
Mon Dec 5 10:13:12 CET 2011


Hi all,

I am running a 'vc-md' calculation with PW.X in QE v4.1.1. The system is bcc-Fe supercell of 16 atoms. The target temperature were set to 600 K in the input file while the temperature goes up all the way to more than 1000 K. I tried with a much larger supercell (128 atoms), this problem still happens.

Does anyone know how to fix this?

Many thanks!
Lily



I attached my input file here:

&control
    calculation='vc-md',

    restart_mode=from_scratch',
    prefix='Fe',
    pseudo_dir = '/pseudo/',
    outdir='/tmp/'
etot_conv_thr = 1d-5,
    forc_conv_thr = 1d-4,
    tprnfor=.true.,

    tstress=.true.,
    dt=10.0,
    nstep=100000
 /
 &system
   nosym=.t., ibrav = 0, celldm(1) =9.3,nat=  16, nbnd=300,ntyp= 1, ecutwfc=40,ecutrho=400,occupations='smearing', smearing='mp', degauss=0.02
 /
 &electrons

mixing_mode='TF'

mixing_beta= 0.7
 /
 &ions
    ion_dynamics='beeman'

    ion_temperature='rescaling'  !  method of temperature control
    tempw=600,         !  target temperature
    tolp=30            !  tolerance for the temperature
/

 &cell
    cell_dynamics='pr'

    press=2000,
 /
ATOMIC_SPECIES
Fe    55.847  Fe.pbe-sp-van.UPF
CELL_PARAMETERS {cubic}
1.00 0.00 0.00
0.00 1.00 0.00
0.00 0.00 1.00
ATOMIC_POSITIONS {crystal}
Fe      0       0       0
Fe      0.25    0.25    0.25
Fe      0.5     0       0
Fe      0.75    0.25    0.25
Fe      0       0.5     0
Fe      0.25    0.75    0.25
Fe      0.5     0.5     0
Fe      0.75    0.75    0.25
Fe      0       0       0.5
Fe      0.25    0.25    0.75
Fe      0.5     0       0.5
Fe      0.75    0.25    0.75
Fe      0       0.5     0.5
Fe      0.25    0.75    0.75
Fe      0.5     0.5     0.5
Fe      0.75    0.75    0.75
K_POINTS { automatic }
4 4 4 0 0 0

Here is the temperature values during the MD
     Ekin =     0.08550401 Ry    T =    0.0 K  Etot = -3974.76493424
     Ekin =     0.08545553 Ry    T =  529.1 K  Etot = -3974.76491196
     Ekin =     0.08523972 Ry    T =  528.4 K  Etot = -3974.76491592
     Ekin =     0.08488325 Ry    T =  527.5 K  Etot = -3974.76492105
     Ekin =     0.08438872 Ry    T =  526.2 K  Etot = -3974.76492687
     Ekin =     0.08375063 Ry    T =  524.7 K  Etot = -3974.76494262
     Ekin =     0.08298072 Ry    T =  522.9 K  Etot = -3974.76496009
     Ekin =     0.08208596 Ry    T =  520.8 K  Etot = -3974.76497988
     Ekin =     0.08108295 Ry    T =  518.4 K  Etot = -3974.76499060
     Ekin =     0.07996422 Ry    T =  515.9 K  Etot = -3974.76500658
     Ekin =     0.07874892 Ry    T =  513.0 K  Etot = -3974.76501879
     Ekin =     0.07744342 Ry    T =  510.0 K  Etot = -3974.76502953
     Ekin =     0.07604792 Ry    T =  506.7 K  Etot = -3974.76504879
     Ekin =     0.07458876 Ry    T =  503.3 K  Etot = -3974.76506076
     Ekin =     0.07307428 Ry    T =  499.6 K  Etot = -3974.76507026
     Ekin =     0.07151519 Ry    T =  495.8 K  Etot = -3974.76507785
     Ekin =     0.06992683 Ry    T =  491.9 K  Etot = -3974.76508190
     Ekin =     0.06831764 Ry    T =  487.9 K  Etot = -3974.76508757
     Ekin =     0.06669444 Ry    T =  483.7 K  Etot = -3974.76510303
     Ekin =     0.06507583 Ry    T =  479.5 K  Etot = -3974.76512546
     Ekin =     0.06348366 Ry    T =  475.1 K  Etot = -3974.76514805
     Ekin =     0.06193603 Ry    T =  470.8 K  Etot = -3974.76516928
     Ekin =     0.06044488 Ry    T =  466.4 K  Etot = -3974.76519330
     Ekin =     0.05903489 Ry    T =  462.0 K  Etot = -3974.76521261
     Ekin =     0.05771662 Ry    T =  457.6 K  Etot = -3974.76523302
     Ekin =     0.05651069 Ry    T =  453.3 K  Etot = -3974.76525200
     Ekin =     0.05543666 Ry    T =  449.1 K  Etot = -3974.76526613
     Ekin =     0.05451365 Ry    T =  445.0 K  Etot = -3974.76527508
     Ekin =     0.05374637 Ry    T =  441.0 K  Etot = -3974.76528988
     Ekin =     0.05315721 Ry    T =  437.1 K  Etot = -3974.76530747
     Ekin =     0.05277633 Ry    T =  433.4 K  Etot = -3974.76531355
     Ekin =     0.05261350 Ry    T =  429.9 K  Etot = -3974.76531535
     Ekin =     0.05268058 Ry    T =  426.7 K  Etot = -3974.76531828
     Ekin =     0.05299435 Ry    T =  423.7 K  Etot = -3974.76532130
     Ekin =     0.05356950 Ry    T =  421.0 K  Etot = -3974.76532740
     Ekin =     0.05441763 Ry    T =  418.6 K  Etot = -3974.76534001
     Ekin =     0.05556545 Ry    T =  416.5 K  Etot = -3974.76534845
     Ekin =     0.05702061 Ry    T =  414.8 K  Etot = -3974.76535951
     Ekin =     0.05880261 Ry    T =  413.5 K  Etot = -3974.76536810
     Ekin =     0.06092253 Ry    T =  412.6 K  Etot = -3974.76537615
     Ekin =     0.06339679 Ry    T =  412.1 K  Etot = -3974.76538052
     Ekin =     0.06622640 Ry    T =  412.0 K  Etot = -3974.76539202
     Ekin =     0.06943072 Ry    T =  412.4 K  Etot = -3974.76540230
     Ekin =     0.07301810 Ry    T =  413.4 K  Etot = -3974.76541371
     Ekin =     0.07700134 Ry    T =  414.8 K  Etot = -3974.76542210
     Ekin =     0.08139225 Ry    T =  416.8 K  Etot = -3974.76542358
     Ekin =     0.08618992 Ry    T =  419.3 K  Etot = -3974.76542521
     Ekin =     0.09139929 Ry    T =  422.4 K  Etot = -3974.76542710
     Ekin =     0.09702375 Ry    T =  426.2 K  Etot = -3974.76542895
     Ekin =     0.10306465 Ry    T =  430.5 K  Etot = -3974.76543106
     Ekin =     0.10952168 Ry    T =  435.4 K  Etot = -3974.76543338
     Ekin =     0.11639279 Ry    T =  441.0 K  Etot = -3974.76543565
     Ekin =     0.12367355 Ry    T =  447.3 K  Etot = -3974.76543806
     Ekin =     0.13135747 Ry    T =  454.2 K  Etot = -3974.76544066
     Ekin =     0.13943498 Ry    T =  461.8 K  Etot = -3974.76544481
     Ekin =     0.14789548 Ry    T =  470.0 K  Etot = -3974.76545002
     Ekin =     0.15672727 Ry    T =  478.9 K  Etot = -3974.76545493
     Ekin =     0.16591506 Ry    T =  488.6 K  Etot = -3974.76545971
     Ekin =     0.17544087 Ry    T =  498.9 K  Etot = -3974.76546486
     Ekin =     0.18528602 Ry    T =  509.9 K  Etot = -3974.76546866
     Ekin =     0.19542620 Ry    T =  521.5 K  Etot = -3974.76547325
     Ekin =     0.20583571 Ry    T =  533.9 K  Etot = -3974.76547954
     Ekin =     0.21647613 Ry    T =  546.9 K  Etot = -3974.76549741
     Ekin =     0.22730110 Ry    T =  560.5 K  Etot = -3974.76554452
     Ekin =     0.23831627 Ry    T =  574.8 K  Etot = -3974.76558181
     Ekin =     0.24947252 Ry    T =  589.8 K  Etot = -3974.76562279
     Ekin =     0.26074557 Ry    T =  605.3 K  Etot = -3974.76565485
     Ekin =     0.27207612 Ry    T =  621.4 K  Etot = -3974.76569597
     Ekin =     0.28344542 Ry    T =  638.1 K  Etot = -3974.76572250
     Ekin =     0.29479651 Ry    T =  655.3 K  Etot = -3974.76574618
     Ekin =     0.30606129 Ry    T =  673.0 K  Etot = -3974.76579053
     Ekin =     0.31721730 Ry    T =  691.2 K  Etot = -3974.76582817
     Ekin =     0.32824936 Ry    T =  709.8 K  Etot = -3974.76582822
     Ekin =     0.33906198 Ry    T =  728.8 K  Etot = -3974.76583611
     Ekin =     0.34961260 Ry    T =  748.2 K  Etot = -3974.76584414
     Ekin =     0.35984903 Ry    T =  768.0 K  Etot = -3974.76585498
     Ekin =     0.36972011 Ry    T =  788.0 K  Etot = -3974.76587088
     Ekin =     0.37917783 Ry    T =  808.2 K  Etot = -3974.76589051
     Ekin =     0.38818195 Ry    T =  828.7 K  Etot = -3974.76590575
     Ekin =     0.39668256 Ry    T =  849.3 K  Etot = -3974.76591947
     Ekin =     0.40463122 Ry    T =  870.0 K  Etot = -3974.76593441
     Ekin =     0.41198588 Ry    T =  890.7 K  Etot = -3974.76594819
     Ekin =     0.41870194 Ry    T =  911.5 K  Etot = -3974.76596318
     Ekin =     0.42474052 Ry    T =  932.2 K  Etot = -3974.76597798
     Ekin =     0.43006276 Ry    T =  952.8 K  Etot = -3974.76599394
     Ekin =     0.43463419 Ry    T =  973.2 K  Etot = -3974.76601082
     Ekin =     0.43842410 Ry    T =  993.5 K  Etot = -3974.76602797
     Ekin =     0.44140452 Ry    T = 1013.5 K  Etot = -3974.76604568
     Ekin =     0.44355191 Ry    T = 1033.2 K  Etot = -3974.76606390
     Ekin =     0.44484735 Ry    T = 1052.5 K  Etot = -3974.76608252
     Ekin =     0.44527696 Ry    T = 1071.5 K  Etot = -3974.76610132
     Ekin =     0.44483203 Ry    T = 1089.9 K  Etot = -3974.76612027
     Ekin =     0.44350967 Ry    T = 1108.0 K  Etot = -3974.76613930
     Ekin =     0.44131301 Ry    T = 1125.4 K  Etot = -3974.76615836
     Ekin =     0.43825157 Ry    T = 1142.3 K  Etot = -3974.76617740
     Ekin =     0.43434138 Ry    T = 1158.6 K  Etot = -3974.76619636
     Ekin =     0.42960510 Ry    T = 1174.2 K  Etot = -3974.76621514
     Ekin =     0.42407189 Ry    T = 1189.2 K  Etot = -3974.76623361
     Ekin =     0.41777725 Ry    T = 1203.5 K  Etot = -3974.76625163
     Ekin =     0.41076253 Ry    T = 1217.0 K  Etot = -3974.76626910
     Ekin =     0.19721000 Ry    T = 1221.1 K  Etot = -3974.97458774
     Ekin =     0.19183941 Ry    T = 1204.4 K  Etot = -3974.97459002
     Ekin =     0.18636543 Ry    T = 1187.6 K  Etot = -3974.97459773
     Ekin =     0.18083022 Ry    T = 1170.6 K  Etot = -3974.97460510
     Ekin =     0.17526808 Ry    T = 1153.5 K  Etot = -3974.97461296
     Ekin =     0.16971356 Ry    T = 1136.4 K  Etot = -3974.97462467
     Ekin =     0.16420699 Ry    T = 1119.3 K  Etot = -3974.97463108
     Ekin =     0.15877522 Ry    T = 1102.3 K  Etot = -3974.97464047
     Ekin =     0.15345494 Ry    T = 1085.4 K  Etot = -3974.97464581
     Ekin =     0.14826952 Ry    T = 1068.6 K  Etot = -3974.97465340
     Ekin =     0.14324982 Ry    T = 1052.1 K  Etot = -3974.97466117
     Ekin =     0.13842282 Ry    T = 1035.9 K  Etot = -3974.97466503
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