[Pw_forum] Computing Second order response

Stefano Baroni baroni at sissa.it
Tue Jun 1 08:11:21 CEST 2010


what's the gap of the unperturbed system?
SB

On May 31, 2010, at 6:10 PM, loc duong ding wrote:

> Dear all,
> 
> I want calculated IR and Raman of nanoribbon. The problem is when the code calcualtion second order response, it is not convergence. 
> 
> This is the output: 
> 
> 
>   Calling punch_plot_e
>     Writing on file  drho                                                                                                                                                                                                                                              
> 
>     Computing Pc [DH,Drho] |psi>
> 
>     Derivative coefficient:  0.001000    Threshold: 1.00E-12
>     Non-scf  u_k: avg # of iterations = 23.5
>     Non-scf Du_k: avg # of iterations = 37.6
> 
>          Dielectric constant from finite-differences
> 
>          (       1.626169126      -0.012354543       0.000000672 )
>          (      -0.012354543       1.773889718      -0.001492007 )
>          (       0.000000672      -0.001492007       1.106263603 )
> 
>     Computing Second order response
> 
> 
>      iter #   1   av.it.:  10.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.194E+04
> 
> 
>      iter #   2   av.it.:  15.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.509E+09
> 
> 
>      iter #   3   av.it.:  15.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.134E+07
> 
> 
>      iter #   4   av.it.:  12.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.986E+03
> 
> 
>      iter #   5   av.it.:  11.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.693E+01
> 
> 
>      iter #   6   av.it.:  14.3
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.269E+04
> 
> 
>      iter #   7   av.it.:  13.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.154E+02
> 
> 
>      iter #   8   av.it.:  12.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.631E+01
> 
> 
>      iter #   9   av.it.:  11.5
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.136E+00
> 
> 
>      iter #  10   av.it.:  10.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.116E+02
> 
> 
>      iter #  11   av.it.:  10.0
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.598E+00
> 
> 
>      iter #  12   av.it.:   9.3
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.220E+00
> 
> 
>      iter #  13   av.it.:  10.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.416E+01
> 
> 
>      iter #  14   av.it.:  10.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.340E+00
> 
> 
>      iter #  15   av.it.:  10.0
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.648E+01
> 
> 
>      iter #  16   av.it.:  11.0
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.214E+02
> 
> 
>      iter #  17   av.it.:  12.3
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.152E+03
> 
> 
>      iter #  18   av.it.:  12.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.314E-01
> 
> 
>      iter #  19   av.it.:  12.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.538E+02
> 
> 
>      iter #  20   av.it.:  11.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.744E+01
> 
> 
>      iter #  21   av.it.:  13.0
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.150E+04
> 
> 
>      iter #  22   av.it.:  13.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.426E+03
> 
> 
>      iter #  23   av.it.:  12.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.238E+03
> 
> 
>      iter #  24   av.it.:  17.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.143E+07
> 
> 
>      iter #  25   av.it.:  15.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.118E+06
> 
> 
>      iter #  26   av.it.:  18.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.122E+08
> 
> 
>      iter #  27   av.it.:  19.3
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.361E+07
> 
> 
>      iter #  28   av.it.:  19.5
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.447E+08
> 
> 
>      iter #  29   av.it.:  22.5
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.186E+11
> 
> 
>      iter #  30   av.it.:  23.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.390E+10
> 
> 
>      iter #  31   av.it.:  25.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.538E+12
> 
> 
>      iter #  32   av.it.:  25.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.231E+12
> 
> 
>      iter #  33   av.it.:  27.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.105E+14
> 
> 
>      iter #  34   av.it.:  30.5
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.700E+15
> 
> 
>      iter #  35   av.it.:  31.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.228E+15
> 
> 
>      iter #  36   av.it.:  31.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.362E+17
> 
> 
>      iter #  37   av.it.:  34.0
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.201E+17
> 
> 
>      iter #  38   av.it.:  35.8
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.245E+19
> 
> 
>      iter #  39   av.it.:  38.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.370E+20
> 
> 
>      iter #  40   av.it.:  37.7
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.172E+20
> 
> 
>      iter #  41   av.it.:  41.2
>      thresh= 0.100E-01 alpha_mix =  0.700 |ddv_scf|^2 =  0.300E+22
> 
> Could you give me some instructions to overcome this problem? 
> 
> I appreciate to all your helps.
> 
> sincerely,
> -----------------------------------------------
> Loc Duong Dinh
> Ms-Ph.D Student
> Sungkyunkwan Advanced Institute of Nanotechnology,
> Sungkyunkwan University,
> Suwon, 440-746, Korea 
> Email: mambom1902 at yahoo.com, ddloc at skku.edu
> 
> 
> 
> 
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---
Stefano Baroni - SISSA  &  DEMOCRITOS National Simulation Center - Trieste
http://stefano.baroni.me [+39] 040 3787 406 (tel) -528 (fax) / stefanobaroni (skype)

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