[Pw_forum] Titanium atomic positions

udayagiri sai babu udayagiri3 at gmail.com
Wed Sep 2 20:52:29 CEST 2009


i am sorry for the previous message which i could not type completely.T his
is what i mean

for the ATOMIC_POSITIONS if you choose "crystal" your lattice coordinates
are correct
Ti 0.3333  0.6666  0.2500
Ti 0.6666  0.3333  0.7500

or else you can represent same as
ATOMIC_POSITIONS (crystal)
Ti 0 0 0
Ti 0.333333  0.666666  0.500000
both are same except they are displaced by (1/3,2/3,1/4)

On Thu, Sep 3, 2009 at 12:18 AM, udayagiri sai babu <udayagiri3 at gmail.com>wrote:

> for the ATOMIC_POSITIONS if you choose "crystal" your lattice coordinates
> are correct
> Ti 0.3333  0.6666  0.2500
> Ti 0.6666  0.3333  0.7500
>
> or else you can represent same as
> ATOMIC_POSITIONS (crystal)
> Ti 0  0.2500
> Ti 0.6666  0.3333  0.7500
>
> On Wed, Sep 2, 2009 at 9:28 PM, Giovanni Cantele <
> Giovanni.Cantele at na.infn.it> wrote:
>
>> Bertrand SITAMTZE wrote:
>> > Dear Giovanni,
>> >
>> > My coordinates are those taken from 2c position of
>> > the crystallographic space group  table. I though these correspond to
>> > the default (alat) in quantum espresso,
>> > in which case mentioning is not mandatory. Isn't it?
>> >
>> > Thanks once more
>> >
>>
>> It is not mandatory to specify the default, but I'm not very sure that
>> your coordinates are in alat units. From
>> http://cst-www.nrl.navy.mil/lattice/struk/a3.html
>> I understand that (1/3,2/3,1/4) and (2/3,1/3,3/4) are in terms of the
>> A1, A2 and A3 vectors rather than
>> the x, y z axes versors. alat positions are cartesian coordinates (in
>> unit of celldm(1)), which are the same as crystal coordinates only for a
>> simple cubic lattice.
>>
>> If I'm not wrong, as pointed out by someone else, you should check that
>> the A1, A2, A3 choice shown in the
>> above link is the same as in Quantum-ESPRESSO (for the latter please
>> have a look to Doc/INPUT_PW* ). If not, you may specify your own lattice
>> vectors by using the CELL_PARAMETERS card.
>>
>> Giovanni
>>
>>
>> >
>> > --- En date de : *Mer 2.9.09, Giovanni Cantele
>> > /<Giovanni.Cantele at na.infn.it>/* a écrit :
>> >
>> >
>> >     De: Giovanni Cantele <Giovanni.Cantele at na.infn.it>
>> >     Objet: Re: [Pw_forum] Titanium atomic positions
>> >     À: "PWSCF Forum" <pw_forum at pwscf.org>
>> >     Date: Mercredi 2 Septembre 2009, 16h48
>> >
>> >     Beside the check of the hcp unit cell, which is crucial, I also
>> guess
>> >     that you gave the input positions
>> >     in "crystal" units, didn't you? If it is the case, I think that you
>> >     should add the "{ crystal }" string after ATOMIC_POSITIONS.
>> >     Indeed, the
>> >     default is "alat" units, I think, namely, cartesian coordinates in
>> >     celldm(1) units.
>> >
>> >     Also do not forget to check the convergence of your results with
>> >     respect
>> >     to ecutrho. The default value (4*ecutwfc) must be usually
>> >     increased (6
>> >     to 12 times ecutwfc) if, as in you case, ultrasoft
>> >     pseudopotentials are
>> >     used.
>> >
>> >     Giovanni
>> >
>> >
>> >     Hande Ustunel wrote:
>> >     > Dear Bertrand,
>> >     >
>> >     > Your atomic positions are rather off with a large gap between
>> >     rumpled Ti
>> >     > layers. Perhaps you should double-check that your definition of
>> >     the hcp
>> >     > unit cell matches that for ibrav=4 in the code. You can find this
>> >     > information in the Doc directory in your copy of espresso.
>> >     >
>> >     > Besides, you should be able to check your structure for yourself
>> >     using
>> >     > xcrysden (--pwi option).
>> >     >
>> >     > Best wishes,
>> >     > Hande
>> >     >
>> >     > On Wed, 2 Sep 2009, Bertrand SITAMTZE wrote:
>> >     >
>> >     >
>> >     >> Dear all,
>> >     >>
>> >     >> Titanium belongs to the     hexagonal P63/mmc
>> >     >> (n° 194) space group. I would like somebody to confirm that my
>> >     attached
>> >     >> input section concerning the bravais lattice and specially the
>> >     atomic positions are good.
>> >     >>
>> >     >> &SYSTEM
>> >     >> ibrav=4
>> >     >> celldm(1)=5.576203
>> >     >> celldm(3)=1.587874
>> >     >> nat=2
>> >     >> ntyp=1
>> >     >> ecutwfc=40.0
>> >     >> /
>> >     >> &ELECTRONS
>> >     >> diagonalization='cg'
>> >     >> /
>> >     >> ATOMIC_SPECIES
>> >     >> Ti 47.867 Ti.pw91-nsp-van.UPF
>> >     >> ATOMIC_POSITIONS
>> >     >> Ti 0.3333  0..6666  0.2500
>> >     >> Ti 0.6666  0.3333  0.7500
>> >     >> K_POINTS automatic
>> >     >> 8 8 4 0 0 0
>> >     >>
>> >     >>
>> >     >> Best regards
>> >
>> >      *********************
>> >     Bertrand SITAMTZE
>> >     PhD student
>> >     Department of Physics
>> >     University of Yaoundé I-Cameroon
>> >      ***********************
>> >
>> >
>> > ------------------------------------------------------------------------
>> >
>> > _______________________________________________
>> > Pw_forum mailing list
>> > Pw_forum at pwscf.org
>> > http://www.democritos.it/mailman/listinfo/pw_forum
>> >
>>
>>
>> --
>>
>>
>>
>> Dr. Giovanni Cantele
>> Coherentia CNR-INFM and Dipartimento di Scienze Fisiche
>> Universita' di Napoli "Federico II"
>> Complesso Universitario di Monte S. Angelo - Ed. 6
>> Via Cintia, I-80126, Napoli, Italy
>> Phone: +39 081 676910
>> Fax:   +39 081 676346
>> E-mail: giovanni.cantele at cnr.it
>>        giovanni.cantele at na.infn.it
>> Web: http://people.na.infn.it/~cantele<http://people.na.infn.it/%7Ecantele>
>> Research Group: http://www.nanomat.unina.it
>> Skype contact: giocan74
>>
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>>
>
>
>
> --
> U.Saibabu
> PhD student,
> Deformation mechanisms modeling group,
> Materials engineering department,
> IISc Bangalore,
> India.
>
>


-- 
U.Saibabu
PhD student,
Deformation mechanisms modeling group,
Materials engineering department,
IISc Bangalore,
India.
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