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<div class="" style="word-wrap:break-word; line-break:after-white-space">Dear all,
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<div class="">I observed that question marks (?) appear in the middle of band representations (see below).</div>
<div class="">It seems similar problem occurs for the last band in some cases ( <a href="https://www.mail-archive.com/users@lists.quantum-espresso.org/msg31534.html" class="">https://www.mail-archive.com/users@lists.quantum-espresso.org/msg31534.html</a> ),
 but I can’t guess the reason for this case.</div>
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<div class="">The material is GaAs with space group F-43m (216) and I attach scf input.</div>
<div class="">Does anyone know why they are not classified properly?</div>
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<div class="">The below excerpt is on the path along Gamma to L.</div>
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<span class="" style=""> **************************************************************************</span></div>
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<span class="" style="">                    xk=(   0.00641,   0.00641,   0.00641  )</span></div>
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<span class="" style="">     double point group C_3v (3m) </span></div>
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<span class="" style="">     there are  6 classes and  3 irreducible representations</span></div>
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<span class="" style="">     the character table:</span></div>
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<span class="" style="">       E     -E    2C3   -2C3  3s_v  -3s_v</span></div>
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<span class="" style="">G_4    2.00 -2.00  1.00 -1.00  0.00  0.00</span></div>
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<span class="" style="">G_5    1.00 -1.00 -1.00  1.00  0.00  0.00</span></div>
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<span class="" style="">G_6    1.00 -1.00 -1.00  1.00  0.00  0.00</span></div>
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<span class="" style="">     imaginary part</span></div>
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<span class="" style="">       E     -E    2C3   -2C3  3s_v  -3s_v</span></div>
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<span class="" style="">G_4    0.00  0.00  0.00  0.00  0.00  0.00</span></div>
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<span class="" style="">G_5    0.00  0.00  0.00  0.00  1.00 -1.00</span></div>
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<span class="" style="">G_6    0.00  0.00  0.00  0.00 -1.00  1.00</span></div>
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<span class="" style="">     the symmetry operations in each class and the name of the first element:</span></div>
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<span class="" style="">     E             1</span></div>
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<span class="" style="">     -E           -1</span></div>
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<span class="" style="">     2C3           2    3</span></div>
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<span class="" style="">     -2C3         -2   -3</span></div>
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<span class="" style="">     3s_v          4    5   -6</span></div>
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<span class="" style="">     3s_v          6   -4   -5</span></div>
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<span class="" style="">     Band symmetry, C_3v (3m)   double point group:</span></div>
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<span class="" style="">     e(  1 -  3) =     -8.82709  eV     3   --> G_4   L_6</span></div>
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<span class="" style="">     e(  1 -  3) =     -8.82709  eV     3   -->   ?</span></div>
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<span class="" style="">     e(  4 -  4) =     -8.82688  eV     1   -->   ?</span></div>
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<span class="" style="">     e(  5 -  6) =     -8.39671  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e(  7 -  9) =     -8.35227  eV     3   --> G_4   L_6</span></div>
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<span class="" style="">     e(  7 -  9) =     -8.35227  eV     3   -->   ?</span></div>
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<span class="" style="">     e( 10 - 10) =     -8.35203  eV     1   -->   ?</span></div>
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<span class="" style="">     e( 11 - 12) =     -6.25322  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 13 - 14) =      5.88934  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 15 - 16) =      6.17226  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 17 - 17) =      6.22576  eV     1   -->   ?</span></div>
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<span class="" style="">     e( 18 - 18) =      6.22593  eV     1   -->   ?</span></div>
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<span class="" style="">     e( 19 - 20) =      6.33992  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 21 - 22) =      9.71086  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 23 - 24) =      9.90063  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 25 - 26) =      9.90114  eV     2   --> G_5   L_4</span></div>
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<span class="" style="">     e( 25 - 26) =      9.90114  eV     2   --> G_6   L_5</span></div>
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<span class="" style="">     e( 27 - 28) =     13.62609  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 29 - 29) =     16.14546  eV     1   -->   ?</span></div>
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<span class="" style="">     e( 30 - 31) =     16.14624  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 32 - 32) =     16.14710  eV     1   -->   ?</span></div>
</div>
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<span class="" style="">     e( 33 - 34) =     17.64099  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 35 - 36) =     17.67265  eV     2   --> G_4   L_6</span></div>
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<span class="" style=""> **************************************************************************</span></div>
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</span></div>
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<span class="" style=""> **************************************************************************</span></div>
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<span class="" style="">                    xk=(   0.01282,   0.01282,   0.01282  )</span></div>
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<span class="" style="">     Band symmetry, C_3v (3m)   double point group:</span></div>
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<span class="" style="">     e(  1 -  1) =     -8.82718  eV     1   -->   ?</span></div>
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<span class="" style="">     e(  2 -  3) =     -8.82700  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e(  4 -  4) =     -8.82677  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e(  5 -  6) =     -8.39672  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e(  7 -  7) =     -8.35236  eV     1   -->   ?</span></div>
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<span class="" style="">     e(  8 -  9) =     -8.35219  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 10 - 10) =     -8.35190  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 11 - 12) =     -6.25187  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 13 - 14) =      5.85998  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 15 - 16) =      6.11074  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 17 - 17) =      6.22366  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 18 - 18) =      6.22401  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 19 - 20) =      6.42336  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 21 - 22) =      9.71374  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 23 - 24) =      9.90214  eV     2   --> G_4   L_6</span></div>
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<span class="" style="">     e( 25 - 26) =      9.90418  eV     2   --> G_5   L_4</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 25 - 26) =      9.90418  eV     2   --> G_6   L_5</span></div>
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<span class="" style="">     e( 27 - 28) =     13.63476  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 29 - 29) =     16.13092  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 30 - 31) =     16.13239  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 32 - 32) =     16.13413  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 33 - 34) =     17.64113  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 35 - 36) =     17.68244  eV     2   --> G_4   L_6</span></div>
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</div>
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<span class="" style=""> **************************************************************************</span></div>
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<span class="" style=""> **************************************************************************</span></div>
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<span class="" style=""></span><br class="">
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<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">                    xk=(   0.01923,   0.01923,   0.01923  )</span></div>
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<span class="" style=""></span><br class="">
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<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     Band symmetry, C_3v (3m)   double point group:</span></div>
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<span class="" style=""></span><br class="">
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<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e(  1 -  1) =     -8.82726  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e(  2 -  3) =     -8.82701  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e(  4 -  4) =     -8.82664  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e(  5 -  6) =     -8.39674  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e(  7 -  7) =     -8.35240  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e(  8 -  9) =     -8.35222  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 10 - 10) =     -8.35171  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 11 - 12) =     -6.24960  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 13 - 14) =      5.80725  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 15 - 16) =      6.06587  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 17 - 17) =      6.22024  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 18 - 18) =      6.22076  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 19 - 20) =      6.50855  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 21 - 22) =      9.71854  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 23 - 24) =      9.90470  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 25 - 25) =      9.90923  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 26 - 26) =      9.90934  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 27 - 28) =     13.64913  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 29 - 29) =     16.10805  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 30 - 31) =     16.11011  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 32 - 32) =     16.11272  eV     1   -->   ?</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 33 - 34) =     17.63003  eV     2   --> G_4   L_6</span></div>
<div class="" style="margin:0px; font-size:11px; line-height:normal; font-family:Menlo">
<span class="" style="">     e( 35 - 36) =     17.70956  eV     2   --> G_4   L_6</span></div>
<div class=""><span class="" style="">
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<span class="" style=""> **************************************************************************</span></div>
<div class=""><span class="" style=""><br class="">
</span></div>
</span></div>
</span></div>
</span></div>
<div class="">Best regards,<br class="">
<div class="">
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<div class="">============================================</div>
<div class="">Minkyu Park</div>
<div class="">Research Institute of Basic Sciences, University of Ulsan,</div>
<div class="">93, Daehak-ro, Nam-gu, Ulsan, 44610 Republic of Korea</div>
<div class=""><a href="mailto:minkyupark@ulsan.ac.kr" class="">minkyupark@ulsan.ac.kr</a></div>
<div class="">+82-52-259-1473</div>
<div class="">============================================</div>
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