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Respected Members,<br><br>Need guidance to reach converge in case of Ni111-3 layer system. I've been modifying input file to reach convergence. The structure file and total energies, scf correction etc. are mentioned below. <br><br> &control<br>    calculation='relax'<br>    restart_mode='from_scratch'<br>    pseudo_dir = '/share/QE_pseudo'<br>    outdir='./'<br>    prefix='Graphane'<br>    forc_conv_thr=1.0D-4<br>!   dt = 20<br>!   tefield = .true.<br>    nstep=10000<br>/<br> &system<br>    ibrav=  0<br>    nat=  12,  ntyp= 1<br>    nspin =2<br>    starting_magnetization(1) = 3<br>    ecutwfc =60.0<br>    occupations='smearing'<br>    degauss=0.002<br>/<br> &electrons<br>!   conv_thr=1.0D-8<br>    mixing_mode='plain'<br>    scf_must_converge=.false.<br>    mixing_beta=0.1D0<br>!   electron_maxstep=400<br> /<br>&ions<br>   ion_dynamics = 'damp'<br>  /<br>! &cell<br>!    cell_dynamics = 'damp-w'<br>!   cell_factor = 10.1D0<br>/<br>CELL_PARAMETERS {angstrom}<br>   4.628949678  -0.000059278   0.000000171<br>   2.314520462   4.008780752   0.000050258<br>  -0.000002055   0.000164552   15.363102749<br>ATOMIC_SPECIES<br>Ni 58.6934 Ni.pbe-mt_fhi.UPF<br>ATOMIC_POSITIONS {angstrom}<br>Ni       6.185153742   3.646046341   1.348253377<br>Ni       2.712614085   0.304163956   3.137196752<br>Ni       3.868845875   0.973870891   4.923613077<br>Ni       3.868707285   3.646335425&nb
sp;  1.348349557<br>Ni       0.397681999   0.305359478   3.137818635<br>Ni       1.556053191   0.973656938   4.923489587<br>Ni       5.027141343   1.640311285   1.348093705<br>Ni       3.870657487   2.309939961   3.137315885<br>Ni       5.026647342   2.977909685   4.924371542<br>Ni       2.712061470   1.641532191   1.348727685<br>Ni       1.554291792   2.310167576   3.137760015<br>Ni       2.712625276   2.976880170   4.923492121<br>K_POINTS {automatic}<br>  5 5 1 0 0 0<br><br>!    total energy              =    -834.04552747 Ry  <br>!    total energy              =    -834.04325469 Ry<br>!    total energy              =    -834.04425938 Ry<br>!    total energy              =    -834.04556520 Ry<br>!    total energy              =    -834.04556221 Ry<br>!    total energy              =    -834.04560185 Ry<br>!    total energy              =    -834.04580045 Ry<br>!    total energy          
    =    -834.04582115 Ry<br>!    total energy              =    -834.04583776 Ry<br>!    total energy              =    -834.04584253 Ry<br>!    total energy              =    -834.04583029 Ry<br>!    total energy              =    -834.04589055 Ry<br>!    total energy              =    -834.04570016 Ry<br>!    total energy              =    -834.04490235 Ry<br>!    total energy              =    -834.04560042 Ry<br>!    total energy              =    -834.04574493 Ry<br>!    total energy              =    -834.04600448 Ry<br><br>scf.out:     Total force =     0.088206     Total SCF correction =     0.113130<br>scf.out:     Total force =     0.140165     Total SCF correction =     0.037912<br>scf.out:     Total force =     0.092519     Total SCF correction =     0.030267<br>scf.out:     Total force =     0.048388     Total SCF correction = &nbs
p;   0.016446<br>scf.out:     Total force =     0.062745     Total SCF correction =     0.044247<br>scf.out:     Total force =     0.104253     Total SCF correction =     0.116776<br>scf.out:     Total force =     0.053904     Total SCF correction =     0.025717<br>scf.out:     Total force =     0.122921     Total SCF correction =     0.063699<br>scf.out:     Total force =     0.025226     Total SCF correction =     0.027631<br>scf.out:     Total force =     0.011274     Total SCF correction =     0.012270<br>scf.out:     Total force =     0.025677     Total SCF correction =     0.021381<br>scf.out:     Total force =     0.035157     Total SCF correction =     0.034833<br>scf.out:     Total force =     0.063476     Total SCF correction =     0.056687<br>scf.out:     Total force =     0.079490     Total SCF correction =     0.079141<br>scf.out:     Total force =     0.052827     Total SCF correction =     0.069824<br>scf.out:     Total force =     0.064376     Total SCF correction =     0.027837<br>scf.out:     Total force =   
  0.067484     Total SCF correction =     0.037266<br>scf.out:     Total force =     0.015039     Total SCF correction =     0.024648<br>scf.out:     Total force =     0.046140     Total SCF correction =     0.040192<br>scf.out:     Total force =     0.025068     Total SCF correction =     0.017854<br>scf.out:     Total force =     0.020379     Total SCF correction =     0.020046<br>scf.out:     Total force =     0.034212     Total SCF correction =     0.034744<br>scf.out:     Total force =     0.026304     Total SCF correction =     0.033508<br>scf.out:     Total force =     0.083963     Total SCF correction =     0.083887<br>scf.out:     Total force =     0.102462     Total SCF correction =     0.099927<br>scf.out:     Total force =     0.027946     Total SCF correction =     0.029401<br>scf.out:     Total force =     0.044795     Total SCF correction =     0.053232<br>scf.out:     Total force =     0.053163     Total SCF correction =     0.019175<br>scf.out:     Total force =     0.016463     Total SCF correction =     0.01
8985<br>scf.out:     Total force =     0.037059     Total SCF correction =     0.024049<br>scf.out:     Total force =     0.036207     Total SCF correction =     0.033862<br>scf.out:     Total force =     0.253157     Total SCF correction =     0.023862<br><br>Best wishes<br>Masood <br>UNIST, Korea<br>
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