<div dir="ltr">Dear all<div><br></div><div>I was performing an optimizing calculation for the kinetic energy cutoff of  wavefunctions expansion for Cu3N compound with a cubic structure using QE v.5.1.</div><div>Results don't show any convergence neither in total energies nor in differences.</div><div>Here is the table for the calculation result<br></div><div><br></div><div><div>25.out:!    total energy              =    -224.54499924 Ry</div><div>30.out:!    total energy              =    -231.56190061 Ry</div><div>35.out:!    total energy              =    -239.33860506 Ry</div><div>40.out:!    total energy              =    -247.75926085 Ry</div><div>45.out:!    total energy              =    -256.35103303 Ry</div><div>50.out:!    total energy              =    -264.81580643 Ry</div><div>55.out:!    total energy              =    -272.59279950 Ry</div><div>60.out:!    total energy              =    -279.38896704 Ry</div></div><div><br></div><div>I chose these PPs:</div><div><br></div><div><div>Cu.pbe-d-hgh.UPF</div><div>N.pbe-hgh.UPF</div></div><div><br></div><div>and this an input file:</div><div><br></div><div><div>&CONTROL</div><div>  calculation<span class="" style="white-space:pre">                </span>= 'scf'</div><div>  verbosity<span class="" style="white-space:pre">         </span>= 'high'</div><div>  restart_mode<span class="" style="white-space:pre">             </span>= 'from_scratch'</div><div>  wf_collect<span class="" style="white-space:pre">               </span>= .TRUE.</div><div>  nstep<span class="" style="white-space:pre">                    </span>=  100 </div><div>  tstress<span class="" style="white-space:pre">           </span>= .TRUE.</div><div>  tprnfor<span class="" style="white-space:pre">          </span>= .TRUE.</div><div>  outdir<span class="" style="white-space:pre">           </span>= './tmp'</div><div>  prefix<span class="" style="white-space:pre">          </span>= 'Cu3N'                       </div><div>  etot_conv_thr<span class="" style="white-space:pre">             </span>= 0.0001</div><div>  forc_conv_thr<span class="" style="white-space:pre">            </span>= 0.0001</div><div>  pseudo_dir<span class="" style="white-space:pre">               </span>= '/home/rezaei/work/cu_pnictide/pseudo'</div><div>/</div><div>&SYSTEM</div><div>  ibrav<span class="" style="white-space:pre">                  </span>= 1</div><div>  celldm(1)<span class="" style="white-space:pre">             </span>= 7.217</div><div>  nat<span class="" style="white-space:pre">                       </span>= 4</div><div>  ntyp<span class="" style="white-space:pre">                  </span>= 2</div><div>  ecutwfc<span class="" style="white-space:pre">               </span>= 25</div><div>  ecutrho<span class="" style="white-space:pre">              </span>= 100.0</div><div>  occupations<span class="" style="white-space:pre">               </span>= 'smearing'</div><div>  degauss<span class="" style="white-space:pre">              </span>= 0.02D0</div><div>  smearing<span class="" style="white-space:pre">         </span>= 'mv'</div><div>/</div><div>&ELECTRONS</div><div>  electron_maxstep<span class="" style="white-space:pre">      </span>= 100</div><div>  conv_thr<span class="" style="white-space:pre">            </span>= 1.0d-6</div><div>  mixing_mode<span class="" style="white-space:pre">              </span>= 'TF'</div><div>  mixing_beta<span class="" style="white-space:pre">                </span>= 0.7D0</div><div>  diagonalization<span class="" style="white-space:pre">   </span>= 'cg'</div><div>/</div><div>ATOMIC_SPECIES</div><div>  Cu   63.5460  Cu.pbe-d-hgh.UPF</div><div>  N    14.0067  N.pbe-hgh.UPF</div><div>ATOMIC_POSITIONS {alat}</div><div>  N        0.000000000   0.000000000   0.000000000</div><div>  Cu       0.000000000   0.500000000   0.000000000</div><div>  Cu       0.500000000   0.000000000   0.000000000</div><div>  Cu       0.000000000   0.000000000   0.500000000</div><div>K_POINTS {automatic}</div><div>  10 10 10  1 1 1</div></div><div><br></div><div>I appreciate any help in advance.</div><div><br></div><div><div> Best regards,</div><div><br></div>-- <br><div class="gmail_signature"><div dir="ltr"><span><font color="#888888"><span style="font-family:arial,helvetica,sans-serif">Seyed Mojtaba Rezaei Sani<br><br>Institute for Research in Fundamental Sciences (IPM)<br>
School of Nano-Science<br><font><span>Shahid Farbin Alley<br>
                Shahid Lavasani st</span></font><br><font><span><font><span>P.O. Box 19395-5531<br></span></font>Tehran, Iran<br></span></font>Tel: +98 21 2310  (3069)<br></span></font></span></div></div>
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