<div dir="ltr"><div><div><div>Dear All,<br></div> I am trying to calculate IR frequency of NH4Br crystal. In <a href="http://ph.in">ph.in</a> and <a href="http://dynmat.in">dynmat.in</a> I have used asr=.true., and asr='zero-dim' respectively. So, I should get 6 zero frequency due to asr option. But I am getting the following frequencies <br>
<br>-----------------------------------------------------<br># mode [cm-1] [THz] IR<br> 1 -265.41 -7.9566 8.4124<br> 2 -251.33 -7.5346 8.3177<br> 3 -224.98 -6.7446 1.1717<br> 4 -108.27 -3.2458 0.0181<br>
5 -0.00 -0.0000 0.0000<br> 6 -0.00 -0.0000 0.0000<br> 7 -0.00 -0.0000 0.0000<br> 8 0.00 0.0000 0.0000<br> 9 0.00 0.0000 0.0000<br> 10 0.00 0.0000 0.0000<br>
11 192.15 5.7604 0.0005<br> 12 238.67 7.1553 0.4008<br> 13 264.00 7.9144 3.5942<br> 14 293.57 8.8012 0.6786<br> 15 329.56 9.8799 1.7381<br> 16 392.07 11.7539 0.0041<br>
17 409.82 12.2862 0.0005<br> 18 413.05 12.3828 0.0013<br> 19 1088.47 32.6315 1.3513<br> 20 1285.27 38.5313 2.2625<br> 21 1393.04 41.7624 1.9338<br> 22 1433.41 42.9725 3.7008<br>
23 1476.19 44.2550 1.3273<br> 24 1493.99 44.7888 1.1527<br> 25 1597.18 47.8821 0.6625<br> 26 1635.26 49.0238 0.0000<br> 27 1676.34 50.2554 0.0047<br> 28 1686.18 50.5505 0.0000<br>
29 2657.92 79.6825 28.6572<br> 30 2931.08 87.8715 14.0421<br> 31 3056.17 91.6215 0.2991<br> 32 3078.70 92.2970 18.7792<br> 33 3094.15 92.7603 7.0421<br> 34 3148.71 94.3958 61.3242<br>
35 3176.09 95.2167 69.5553<br> 36 3474.05 104.1493 36.0143<br>-----------------------------------------------------------------------------------------------<br><br></div>I am also giving my inputs also <br>
</div>-----------------------------------<br><a href="http://scf.in">scf.in</a><br><div><div>&control<br> calculation = 'scf',<br> title = 'NH4Br'<br> restart_mode = 'from_scratch'<br>
tprnfor = .TRUE.<br> prefix = 'NH4Br',<br> outdir = '------'<br> pseudo_dir = '---------'<br> nstep=1000<br> /<br> &system<br> ibrav = 0,<br> nat = 12,<br> ntyp = 3,<br>
nbnd = 60<br> tot_charge = 0<br> celldm(1) = 1.890359168<br> ecutwfc = 30.00<br> ecutrho = 300.00<br> london = .true.<br> london_s6 = 0.75<br> london_rcut = 200.00<br> /<br> &electrons<br>
electron_maxstep = 1000<br> mixing_beta=0.3<br> conv_thr = 1.0d-8<br> diagonalization='david'<br> diago_david_ndim = 4<br>/<br> &CELL<br> cell_dynamics='bfgs'<br> press = 0.0<br> /<br>ATOMIC_SPECIES<br>
H 1.00794 H.pbe-van_ak.UPF<br> Br 79.904 Br.pbe-van_mit.UPF<br> N 14.0067 N.pbe-van_ak.UPF<br>ATOMIC_POSITIONS angstrom<br>N 0.000000000 0.000000000 0.000000000<br>.<br>.<br>H 0.000000000 4.781723484 3.381166715<br>
K_POINTS automatic<br>6 6 6 0 0 0<br>CELL_PARAMETERS angstrom<br> 5.633079685 0.000000000 0.000000000<br> 0.000000000 5.633079685 0.000000000<br> 0.000000000 0.000000000 3.982678150<br><br><br></div><div>
<a href="http://ph.in">ph.in</a><br><br>&inputph<br> tr2_ph=4.0d-17,<br> prefix='---',<br> outdir='------',<br> amass(1)=1.d0,<br> amass(2)=79.9d0,<br> amass(3)=14.d0,<br> asr=.true.,<br> zue=.true.,<br>
epsil=.true.,<br> trans=.true.,<br> fildyn='NH4Br.dyn.xml',<br> /<br>0.0 0.0 0.0<br><br></div><div><br></div><div><a href="http://dynmat.in">dynmat.in</a><br><br> &input<br> fildyn='NH4Br.dyn.xml',<br>
asr='zero-dim'<br> /<br><br>------------------------------------------------------------------------------------------<br></div><div>Why I am getting such kind of frequencies and how can I solve it? Any suggestions is highly appreciated. <br>
<br></div><div>Thanking you in advance.<br></div><div>Pratik<br></div><div>Kolkata, India<br></div><div><br></div></div></div>