Dear <span style="color:rgb(34,34,34);font-family:arial,sans-serif;font-size:12.727272033691406px;background-color:rgb(255,255,255)">Sanjeev:</span><div><font color="#222222" face="arial, sans-serif">  </font></div><div><font color="#222222" face="arial, sans-serif">> </font>In my guess, the converging mostly depends on choosing pseudopotential, </div>

<div><span style="color:rgb(34,34,34);font-family:arial,sans-serif;font-size:12.727272033691406px;background-color:rgb(255,255,255)">         I  changes the pseudopotential from "C.pw-mt_fhi.UPF" to "C.pz-hgh.UPF" and get the expected "Raman activity" for different </span>ecutwfc<span style="background-color:rgb(255,255,255);color:rgb(34,34,34);font-family:arial,sans-serif;font-size:12.727272033691406px">.</span></div>

<div><span style="background-color:rgb(255,255,255);color:rgb(34,34,34);font-family:arial,sans-serif;font-size:12.727272033691406px">         Thank you very much :)</span></div><div><span style="background-color:rgb(255,255,255);color:rgb(34,34,34);font-family:arial,sans-serif;font-size:12.727272033691406px"><br>

</span></div><div><font color="#222222" face="arial, sans-serif">         The following is my results.</font></div><div><span style="background-color:rgb(255,255,255);color:rgb(34,34,34);font-family:arial,sans-serif;font-size:12.727272033691406px">Using "C.pw-mt_fhi.UPF" :</span></div>

<div><font color="#222222" face="arial, sans-serif"><div><div>ecutwfc(Ry)      Freq(cm-1)          Raman activity(A^4/amu)</div><div> 65                 1330.65                   68.9754      </div><div>100                1330.23                   68.9674      </div>

<div>110                1330.50               3066.0811      </div><div>120                1330.48                   15.1570      </div><div>130                1330.47                   68.9545      </div><div>140                1330.48                   68.9536      </div>

<div>150                1330.48                   68.9541      </div><div><br></div></div><div><br></div><div><div><span style="font-size:12.727272033691406px;background-color:rgb(255,255,255)">Using </span><span style="background-color:rgb(255,255,255);font-size:12.727272033691406px"> </span><span style="background-color:rgb(255,255,255);font-size:12.727272033691406px">"C.pz-hgh.UPF"</span><span style="background-color:rgb(255,255,255);font-size:12.727272033691406px"> :</span></div>

<div><font color="#222222" face="arial, sans-serif"><div><div>ecutwfc(Ry)      Freq(cm-1)          Raman activity(A^4/amu)</div><div> 70               1330.78                  69.6225  </div><div> 90               1341.85                  70.0144  </div>

<div>100              1333.32                  70.1650  </div><div>110              1337.38                  87.7369  </div><div>120              1339.90                  69.9051  </div><div>130              1339.60                  69.9249  </div>

<div>140              1338.35                  69.9469  </div><div>150              1337.71                  69.9402  </div></div><div><br></div></font></div></div></font><br><div class="gmail_quote">On Thu, May 30, 2013 at 12:43 AM, Sanjeev Gupta <span dir="ltr"><<a href="mailto:physics.skgupta@gmail.com" target="_blank">physics.skgupta@gmail.com</a>></span> wrote:<br>

<blockquote class="gmail_quote" style="margin:0 0 0 .8ex;border-left:1px #ccc solid;padding-left:1ex">Dear Wang<div><br></div><div>In my guess, the converging mostly depends on choosing pseudopotential, so may be it is the problem, that you are not getting converge Raman activity.</div>

<div>Otherhand, can you check your structure as well as, but i am not sure.</div>
<div><br></div><div>Best</div><div>Sanjeev</div><div><br><br><div class="gmail_quote"><div><div class="h5">On Wed, May 29, 2013 at 5:22 AM, xirainbow <span dir="ltr"><<a href="mailto:nkxirainbow@gmail.com" target="_blank">nkxirainbow@gmail.com</a>></span> wrote:<br>


</div></div><blockquote class="gmail_quote" style="margin:0 0 0 .8ex;border-left:1px #ccc solid;padding-left:1ex"><div><div class="h5">Dear all:<div>            I calculated the "Raman activity" of diamond(Carbon) using QE-5.0. </div>

<div>            The "Raman activity" changes too much with ecutwfc.</div>
<div>            Could you give me some help?</div>

<div><br></div><div>Calculational results of "Raman activity variation with ecutwfc" ("14*14*14 kmesh).</div><div>   ecutwfc(Ry)      Freq(cm-1)          Raman activity(A^4/amu)</div><div>   65                     1330.23                  68.9754</div>




<div>   100                   1330.65                  68.9674</div><div>   110                   1330.50              3066.0811</div><div>   120                   1330.48                  15.1570</div><div>   130                   1330.47                  68.9545</div>




<div><br></div><div>The following is input of pw.x and ph.x:</div><div>INPUT of SCF:</div><div><div><div> &control</div><div>    calculation='scf',</div><div>    disk_io='low',</div><div>    restart_mode='from_scratch',</div>




<div>    prefix='diamond.$i'</div><div>    pseudo_dir = '/home/lykong/hwang/espresso-5.0/pseudo',</div><div>    outdir='/home/lykong/hwang/tmp'</div><div> /</div><div> &system</div><div>    ibrav = 0, celldm(1) = 1.88972687777436, nat= 2, ntyp= 1,</div>




<div>    ecutwfc = $i</div><div> /</div><div> &electrons</div><div>    mixing_beta = 0.7</div><div>    conv_thr =  1.0d-8</div><div> /</div><div>ATOMIC_SPECIES</div><div> C   12.01   C.pw-mt_fhi.UPF</div><div>ATOMIC_POSITIONS {crystal}</div>




<div>C   0.000000000         0.000000000         0.00000000</div><div>C   0.250000000         0.250000000         0.25000000</div></div></div><div><div>CELL_PARAMETERS</div><div>   1.758613117   1.758613117   0.000000000</div>




<div>   1.758613117   0.000000000   1.758613117</div><div>   0.000000000   1.758613117   1.758613117</div></div><div><br></div><div><br></div><div>INPUT of PHONON:</div><div><div>phonons of diamond at Gamma</div><div> &inputph</div>




<div>  tr2_ph=1.0d-14,</div><div>  alpha_mix=0.7</div><div>  prefix='diamond.$i'</div><div>  epsil=.true.,</div><div>  lraman=.true.,</div><div>  amass(1)=12.01,</div><div>  outdir='/home/lykong/hwang/tmp'</div>




<div>  fildyn='diamond.$i.dynG',</div><div>  reduce_io=.TRUE.</div><div> /</div><div>0.0 0.0 0.0</div></div><span><font color="#888888"><div><br></div><div>           <br clear="all"><div><br></div>
-- <br>____________________________________<br>

Hui Wang<br>School of physics, Fudan University, Shanghai, China
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<br clear="all"><div><br></div>-- <br><div><span style="font-size:13px;font-family:Tahoma">With Best Regards,</span></div>
<div><span style="font-size:13px;font-family:Tahoma"><br></span></div><div><span style="font-size:13px;font-family:Tahoma">------------------------------</span><span style="font-size:13px;font-family:Tahoma">------</span></div>


<div><div style="font-family:Tahoma;font-size:13px"><div style="font-size:13px"><div style="font-size:13px">Dr. Sanjeev Kumar Gupta<br>Fulbright Post-Doctoral Scholar<br>Dept. of Physics<br><span style="line-height:19.49652862548828px;text-align:justify;color:rgb(68,68,68);font-family:'Trebuchet MS',Geneva,sans-serif">Michigan Technological University </span><br>


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Hui Wang<br>School of physics, Fudan University, Shanghai, China
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