To be clear, on my second attempt the bottom of my file looks like :<br><br>/<br> 5<br> 3P 2 1 6.00 0.00 0.50 0.50 0.00<br> 3D 3 2 10.00 0.00 0.50 0.50 0.00 <br> 4S 2 0 2.00 0.00 2.0 2.0 0.00<br> 4P 3 1 1.00 0.00 2.0 2.0 0.00<br>
3S 1 0 2.00 0.00 0.50 0.50 0.00<br><br><br>Thanks,<br>Brad<br><br><div class="gmail_quote">On Sat, Nov 14, 2009 at 6:19 PM, Brad Malone <span dir="ltr"><<a href="mailto:brad.malone@gmail.com">brad.malone@gmail.com</a>></span> wrote:<br>
<blockquote class="gmail_quote" style="border-left: 1px solid rgb(204, 204, 204); margin: 0pt 0pt 0pt 0.8ex; padding-left: 1ex;">Hi, I'm trying to generate a pseudopotential for Gallium with the entire third shell taken as valence (i.e., I want 3s2 3p6 3d10 4s2 4s1 all in valence). I didn't see anything in the /atomic_doc/pseudo_library/ that had an example where there were multiple occupied states of the same angular momentum. My first attempt at doing so was with the following input file:<br>
<br> &input<br> atom = 'Ga'<br> iswitch = 3<br> rel = 1<br> dft = 'PZ'<br>/<br> 8<br> 1S 1 0 2.00 1<br> 2S 2 0 2.00 1<br> 2P 2 1 6.00 1<br> 3S 3 0 2.00 1<br> 3P 3 1 6.00 1<br>
3D 3 2 10.00 1<br> 4S 4 0 2.00 1<br> 4P 4 1 1.00 1<br>&inputp<br> pseudotype = 2<br> file_pseudopw = 'Ga.UPF'<br> lloc = 0<br> nlcc = .false.<br> tm = .true.<br>/<br> 3<br> 3P 2 1 6.00 0.00 0.50 0.50 0.00<br>
3D 3 2 10.00 0.00 0.50 0.50 0.00 <br> 3S 1 0 2.00 0.00 0.50 0.50 0.00<br><br>After generating the pseudopotential with this file, it became clear that I had the wrong valence (no 4s or 4p electrons presumably). So I tried to edit the file and add these in to the &inputp field. For the 4S and 4P I used a cutoff of 2 au, but the pseudopotential generation failed and said that I had the wrong number of nodes. Am I doing something wrong? I appreciate any help or suggestions. Thanks!<br>
<br>Best,<br>Brad <br>UC Berkeley<br><br>
</blockquote></div><br>