hi 2 all,<br><br>I am somewhat confused about construction of a film. like whenever we calculate the band gap of a unit cell of any system and 2*2*2 supercell of that system we get the same value whereas when one moves from nano regime to larger scale the band gap should decrease. It means that the unit cell is treated as crystal.So, if i construct a film , by taking it as 2*2*1 supercell, it will again consider it as sum of crystals and will yield the same results ????? Hope so that my question is clear .. How to make a structure of film ??? Thanks in advance. <br>
With regards,<br>Dev Sharma <br>