<table cellspacing="0" cellpadding="0" border="0" ><tr><td valign="top" style="font: inherit;"><br>Dear all<br><br>From Linear response calculation ,I get for TiO2
bulk U=5.73, But when I double the unit cell in z direction and again
compute U ,I get three different value for Ti atoms.(U=5.63,5.46,5.70).<br>Why these values are not same . what is the main reason? Does it in numerical variation errors?<br>ANother question:<br>When
we perturb D level by alpha, it give rise to change in d occupancy . Is
it correct that if we impose negative alpha , the occupation becomes
less than initial state .?<br>for Ti isolated atom for apha=0.1
tr[ns(na)] after first-iteration equal to the 0.002 and at the end of
calculation is 2.327 while we know that for Ti, tr[ns(na)] =2.000.
Does it seems to be correct.?<br><br> Number of iteration with fixed ns = 0<br> Starting ns and Hubbard U :<br> enter
write_ns<br>U( 1) = 0.0000<br>alpha( 1) = 0.1000<br>atom 1 Tr[ns(na)]= 2.0000000<br>atom 1 spin 1<br>eigenvalues: 0.4000000 0.4000000 0.4000000 0.4000000 0.4000000<br> eigenvectors<br> 1 1.0000000 0.0000000 0.0000000 0.0000000 0.0000000<br> 2 0.0000000 1.0000000 0.0000000 0.0000000 0.0000000<br> 3 0.0000000 0.0000000 1.0000000 0.0000000 0.0000000<br> 4 0.0000000 0.0000000 0.0000000 1.0000000 0.0000000<br> 5 0.0000000 0.0000000 0.0000000 0.0000000 1.0000000<br> occupations<br> 0.400 0.000 0.000 0.000 0.000<br> 0.000 0.400 0.000 0.000 0.000<br> 0.000 0.000 0.400 0.000 0.000<br> 0.000
0.000 0.000 0.400 0.000<br> 0.000 0.000 0.000 0.000 0.400<br>atom 1 spin 2<br>eigenvalues: 0.0000000 0.0000000 0.0000000 0.0000000 0.0000000<br> eigenvectors<br> 1 1.0000000 0.0000000 0.0000000 0.0000000 0.0000000<br> 2 0.0000000 1.0000000 0.0000000 0.0000000 0.0000000<br> 3 0.0000000 0.0000000 1.0000000 0.0000000 0.0000000<br> 4 0.0000000 0.0000000 0.0000000 1.0000000 0.0000000<br> 5 0.0000000 0.0000000 0.0000000 0.0000000 1.0000000<br> occupations<br> 0.000 0.000 0.000 0.000 0.000<br> 0.000 0.000 0.000 0.000 0.000<br> 0.000 0.000 0.000 0.000 0.000<br> 0.000 0.000
0.000 0.000 0.000<br> 0.000 0.000 0.000 0.000 0.000<br>nsum = 2.0000000<br> exit write_ns<br> Atomic wfc used for LDA+U Projector are NOT orthogonalized<br> Starting wfc are 9 atomic + 1 random wfc<br><br> total cpu time spent up to now is 13.34 secs<br><br> per-process dynamical memory: 326.3 Mb<br><br> Self-consistent Calculation<br><br> iteration # 1 ecut= 45.00 Ry beta=0.70<br> CG style diagonalization<br> c_bands: 3 eigenvalues not converged<br> c_bands: 2 eigenvalues not converged<br> ethr = 1.00E-12, avg #
of iterations = 40.4<br> enter write_ns<br>U( 1) = 0.0000<br>alpha( 1) = 0.1000<br>atom 1 Tr[ns(na)]= 0.0021401<br>atom 1 spin 1<br>eigenvalues: 0.0000001 0.0000001 0.0000001 0.0009883 0.0009883<br> eigenvectors<br> 1 0.0000000 -0.8803392 -0.4743427 0.0000000 0.0013927<br> 2 0.0000000 -0.4743432 0.8803400 0.0000000 -0.0000040<br> 3 0.0000000 0.0012242 0.0006642 0.0000000 0.9999990<br> 4 -0.8886820 0.0000000 0.0000000 -0.4585240 0.0000000<br> 5 0.4585240 0.0000000 0.0000000 -0.8886820 0.0000000<br> occupations<br> 0.001 0.000 0.000 0.000 0.000<br> 0.000 0.000 0.000 0.000 0.000<br> 0.000 0.000 0.000 0.000
0.000<br> 0.000 0.000 0.000 0.001 0.000<br> 0.000 0.000 0.000 0.000 0.000<br>---------------------------------- and end of the file is <br>:<br> End of self-consistent calculation<br> enter write_ns<br>U( 1) = 0.0000<br>alpha( 1) = 0.1000<br>atom 1 Tr[ns(na)]= 2.3270531<br>atom 1 spin 1<br>eigenvalues: 0.1574294 0.1574294 0.1574294 0.9273825 0.9273825<br> eigenvectors<br> 1 0.0000000 -0.4359030 -0.7986559 0.0000000 0.4148945<br> 2 0.0000000 0.7269732 -0.0406891 0.0000000 0.6854592<br> 3 0.0000000 -0.5305643 0.6004109 0.0000000 0.5983379<br> 4 -0.9258933 0.0000000 0.0000000 -0.3777851 0.0000000<br> 5 0.3777851 0.0000000 0.0000000
-0.9258933 0.0000000<br> occupations<br> 0.927 0.000 0.000 0.000 0.000<br> 0.000 0.157 0.000 0.000 0.000<br> 0.000 0.000 0.157 0.000 0.000<br> 0.000 0.000 0.000 0.927 0.000<br> 0.000 0.000 0.000 0.000 0.157<br><br><br>Ali Kazempour<br>
Physics department, Isfahan University of Technology<br>
84156 Isfahan, Iran. Tel-1: +98 311 391 3733<br>
Fax: +98 311 391 2376 Tel-2: +98 311 391 2375</td></tr></table><br>