Thanx alot Eyvaz and all .... In fact am still working on it .... please tell me if am wrong but I think the problem is due to different - or lets say - incompatible data between the system input file and the adsorbed oxygen ..... am sending the two input files data as it might help ..... <br>
<br><br><b>The oxygen input file was : </b><br><br>&control<br> calculation='scf',<br> restart_mode='from_scratch',<br> pseudo_dir='/home/new_generation/espresso-3.2/pseudo/'<br> outdir='/home/new_generation/espresso-3.2/tmp/'<br>
prefix = 'O'<br> /<br> &system<br> ibrav=1,<br> celldm(1)=14.0,<br> nat=1,<br> ntyp=1,<br> nbnd=6,<br> nosym=.true.,<br> ecutwfc=27.0,<br> ecutrho=216.0,<br> occupations='from_input',<br>
nspin=2,<br> starting_magnetization(1)=0.5d0,<br> /<br> &electrons<br> mixing_beta=0.25,<br> conv_thr=1.0E-8,<br> /<br>ATOMIC_SPECIES<br>O 15.99994 O.pbe-rrkjus.UPF<br>ATOMIC_POSITIONS <br>O 0.000000000 0.000000000 0.000000000 <br>
K_POINTS (gamma)<br>OCCUPATIONS<br>1.0 1.0 1.0 1.0 0.0 0.0 <br>1.0 0.33333333333 0.33333333333 0.33333333333 0.0 0.0 <br><br>------------------------------------------------------------------------------------------<br><br>
<br><b>And the whole system input file was : </b><br><br>&CONTROL<br> calculation = "scf",<br> restart_mode = 'from_scratch' ,<br> prefix = 'IrO2-OtopIr',<br> outdir = '/home/new_generation/espresso-3.2-2/tmp',<br>
pseudo_dir = '/home/new_generation/espresso-3.2-2/pseudo' <br>/<br>&SYSTEM<br> ibrav = 6, <br> celldm(1) = 8.6714,<br> celldm(3) = 6.923880978, <br> nat = 29,<br> ntyp = 2,<br>
ecutwfc = 55.D0,ecutrho=600.0,<br> occupations = "smearing",<br> smearing = "methfessel-paxton",<br> degauss = 0.03D0,<br>/<br>&ELECTRONS <br> electron_maxstep =300, <br> conv_thr = 1.D-8,<br>
mixing_beta = 0.3D0, <br> startingpot = 'atomic'<br> startingwfc = 'atomic'<br>/<br>&IONS<br> ion_dynamics = 'bfgs',<br>/<br>ATOMIC_SPECIES<br>Ir 192.217 Ir.pbe-n-rrkjus.UPF.txt<br>O 15.999 O.pbe-rrkjus.UPF <br>
ATOMIC_POSITIONS (bohr)<br>Ir 0.000000000 0.000000000 -12.223315777<br>Ir -4.335700000 4.335700000 -9.151253653<br>Ir 0.000000000 0.000000000 -6.022199397<br>Ir -4.335700000 4.335700000 -3.039010085<br>
Ir 0.000000000 0.000000000 0.000000000<br>Ir -4.335700000 4.335700000 3.039010085<br>Ir 0.000000000 0.000000000 6.022199397<br>Ir -4.335700000 4.335700000 9.151253653<br>Ir 0.000000000 0.000000000 12.223315777<br>
O 0.000000000 0.000000000 15.557622468<br>O 0.000000000 0.000000000 -15.557622468<br>O 2.674536021 2.674536021 0.000000000<br>O -2.674536021 -2.674536021 0.000000000<br>O 1.669820608 -1.669820608 -3.018450895<br>
O 1.669820608 -1.669820608 3.018450895<br>O -1.669820608 1.669820608 -3.018450895<br>O -1.669820608 1.669820608 3.018450895<br>O 2.671662729 2.671662729 -6.079652442<br>O 2.671662729 2.671662729 6.079652442<br>
O -2.671662729 -2.671662729 -6.079652442<br>O -2.671662729 -2.671662729 6.079652442<br>O 1.644951111 -1.644951111 -9.029413066<br>O 1.644951111 -1.644951111 9.029413066<br>O -1.644951111 1.644951111 -9.029413066<br>
O -1.644951111 1.644951111 9.029413066<br>O 2.558767457 2.558767457 -11.893600003<br>O 2.558767457 2.558767457 11.893600003<br>O -2.558767457 -2.558767457 -11.893600003<br>O -2.558767457 -2.558767457 11.893600003<br>
K_POINTS (automatic)<br>12 12 1 0 0 0<br><br><br>Please tell me if you can see the problem ..... thanks again<br><br>Have a nice day .<br><font color="#888888"><br>Hashem Al-Yamani<br>Computational physics department<br>Jordan Univ.</font>